HAIR TREATMENT COMPOSITION, HAIR TREATMENT SYSTEM, HAIR TREATMENT AND HAIR COLOR CHANGE METHODS, AND

专利摘要:
the description relates to compositions for treating keratinous substrates, such as hair, comprising at least one monoamine and at least one carboxylic acid, and also to systems and methods for treating keratinous substrates with the compositions.
公开号:BR112018010381B1
申请号:R112018010381-0
申请日:2016-11-24
公开日:2021-08-17
发明作者:Kimberly Christine Dreher；Gerard Provot；Dariusz DANIELSKI；Fabien Pascal Boulineau；Caroline Rahmouna Francoise Goget；Anthony Potin；Allison Chin；Michael DeGeorge；Mara APPLEBAUM；Mary Abraam Soliman；Ashley Ann Figatner；Megan PAUKER；Emmanuel Appiahamponsah
申请人:L'oreal；
IPC主号:

专利说明:

TECHNICAL FIELD
[001] The present description refers to compositions for use in the treatment of keratinous substrates, such as hair. FUNDAMENTALS
[002] It is known that consumers wish to use cosmetic and care compositions that improve the appearance of keratin substrates such as hair, eg, by changing the color, style, and/or shape of the hair, and/or by granting of various properties to the hair, such as shine and conditioning. Many of the known compositions and known processes for improving the appearance of hair involve chemical treatment of hair.
[003] The process of changing the hair color, for example, may involve the deposition of an artificial dye on the hair that provides a different nuance or color to the hair, and/or performs hair color "lifting", such as bleaching from dark hair color to lighter nuances. The process of "lifting" hair color, also known as lightening, generally requires the use of compositions comprising at least one oxidizing agent.
[004] Hair color lightening or "lifting" is typically assessed by varying the height of the shade before and after applying a hair color altering composition to the hair. This variation corresponds to the degree or level of whitening or “lift”. The notion of “hue” is based on the classification of natural hues, a hue separating each hue from the hue immediately after or before it, which is well known by hairdressers. Shade heights or levels range from 1 (black) to 10 (light blonde), one unit corresponding to one shade; therefore, the higher the number, the clearer the nuance or the higher the degree of “lift”.
[005] In general, hair lightening or hair color lifting compositions and hair dyeing compositions have an alkalinity such that these compositions have a pH value above 7, typically being pH 9 and above, and may, in general, require the presence of an alkalizing agent such as ammonia or an ammonia gas generating compound and/or an amine or ammonium-based compound in sufficient amounts to make such compositions alkaline. The alkalizing agent causes the hair to swell, thereby allowing small molecules of oxidative dye to penetrate the cuticle and cortex before the oxidative condensation process is complete. The larger colored complexes resulting from the oxidative reaction are then trapped within the hair fiber, thus permanently changing the hair color.
[006] Additionally, there are many techniques and compositions for styling or changing the shape of hair. For example, hair care products called "hair relaxers" or "hair straighteners" can relax or straighten curly or frizzy hair, including wavy hair. Straightening or relaxing curls of highly curly hair can increase the handleability and ease of styling of such hair. Compositions for permanent hair curling will provide a curl or wave to differently straightened hair. Different types of compositions can be applied to the hair in order to change its shape or make it more manageable, such as alkaline and acid compositions. Relaxers, straighteners, perms and/or hair waves can be applied either at a hair salon by a professional or at home by the individual consumer.
[007] Although dyeing or color lifting compositions can effectively change the color of hair, and relaxation, straightening, perming, and curling compositions can effectively change the shape of hair, these chemical treatments can damage the hair. hair fibers and/or irritate the scalp. Thus, in order to reduce or avoid the above mentioned disadvantages, and also to improve the cosmetic performance of the compositions, the use of new and additional components and new combinations of ingredients is continually aimed at.
[008] However, the choice of components or combinations of ingredients could present difficulties as they cannot be detrimental to other cosmetic attributes such as ease and uniformity of application, viscosity or rheology properties, and stability of the compositions, deposit of dye and target shade formation, and/or result in major disadvantages such as increased damage or a less healthy appearance of hair. It would therefore be desirable to provide the consumer with compositions and methods that can treat the hair, eg, "lift" the hair color and/or deposit dye onto the hair in an efficient manner, while providing other cosmetic advantages such as shine, conditioning , fiber resistance, and/or healthy appearance to hair, while avoiding or minimizing hair damage.
[009] In addition, hair both natural and sensitized or chemically treated may contain various types of negatively charged moieties, for example, carboxylates (resulting from the hydrolysis of amino acids and thioester bonds) and/or sulfonates (resulting from the oxidation of disulfide bonds) . These negatively charged portions can degrade the hair's cosmetic properties.
[0010] Furthermore, when hair is chemically treated or damaged, the disulfide bonds in the hair (disulfide bonds between two cysteine units) can be reduced or broken, resulting in the formation of thiol and/or cysteic acid groups. Cysteine bridges, or disulfide bonds, are the strongest bonds present in the hair's internal network and play a very important role in hair strength. Cosmetic treatments, such as bleaching, straightening, or permanent waving of hair, can permanently alter these bonds causing the formation of cysteic acid. As such, increased amounts of cysteic acid in the hair suggest that the hair is damaged.
[0011] Thus, an aim of the description is to provide new compositions that can provide advantageous effects such as hair fiber strength, protection of hair fibers from further damage or damage, improved properties such as softness, shine, conditioning, healthy appearance, while which, at the same time, provide desired effects such as coloring, whitening, smoothing, relaxing, and/or structuring (shaping change). SUMMARY
[0012] The present description relates to compositions and systems for treating keratinous substrates, such as hair, and, furthermore, methods for treating keratinous substrates with the compositions and systems described herein.
[0013] According to various embodiments, the description refers to compositions for hair treatment comprising at least one monoamine and at least one carboxylic acid. Treatment compositions can optionally be used in conjunction with chemical treatments as compositions or agents for altering the color or shape of hair, including compositions for dyeing hair or for lightening hair, or compositions for structuring (shaping) hair. hair for straightening, relaxing, and/or permanent waving hair, or can be used with hair treatment compositions which are non-color or shape altering compositions. The treatment compositions can also optionally be applied directly to the hair, and/or can be mixed with water or another solvent or other composition, and applied to the hair.
[0014] This description further relates to hair conditioning compositions comprising at least one monoamine and at least one carboxylic acid. In further embodiments, the description relates to hair treatment systems comprising the treatment compositions and conditioning compositions according to the description, and the use of the systems together with the compositions for changing the color and/or shape of hair.
Exemplary methods comprise applying the treatment composition according to the description to the hair prior to, during, and/or after the application to the hair of a color altering composition. Other exemplifying methods comprise applying a conditioning composition, as described, to the hair after applying the treatment composition. The methods as per the description can provide cosmetic advantages such as shine, conditioning, fiber strength, and/or a healthy appearance to dyed hair, and/or prevent or minimize damage to hair that may, under other conditions, occur with processes for hair alteration by dyeing, bleaching or other chemical processes to change the hair color.
Additional exemplifying methods comprise applying the treatment composition according to the description to the hair prior to, during, and/or after the application to the hair of a hair structuring composition. The methods as described can provide cosmetic advantages such as shine, conditioning, fiber strength, and/or a healthy appearance to structured hair, and minimize hair damage that may, under other conditions, occur with processes to alter hair by structuring process or other chemical processes.
[0017] Additional exemplifying methods comprise applying the treatment composition, in accordance with the description, to the hair, prior to, during, and/or after application to the hair, of a composition that is a non-color-altering composition. or the format. Additional exemplary methods comprise applying the treatment composition according to the description to the hair prior to, during, and/or after application to the hair of water or other solvent. The methods as described can provide cosmetic advantages such as shine, conditioning, fiber strength, and/or a healthy appearance to structured hair, and minimize hair damage.
According to various embodiments, the exemplary hair care systems comprise treatment compositions comprising at least one monoamine and at least one carboxylic acid; conditioning compositions comprising monoamine and at least one carboxylic acid; and, optionally, a composition or an agent for altering the color or shape of the hair. In some embodiments, the at least one carboxylic acid in the treatment composition and the at least one carboxylic acid in the conditioning composition of the systems are the same. In some embodiments, the at least one carboxylic acid in the treatment composition and the at least one carboxylic acid in the conditioning composition of the systems are different. Other embodiments of hair care systems comprise treatment compositions comprising 3-methoxypropylamine (3-MPA) and citric acid; conditioning compositions comprising 3-MPA and citric acid; and, optionally, a composition or an agent for altering the color or shape of the hair. Still other modalities of hair care systems comprise treatment compositions comprising 3-MPA and citric acid and/or maleic acid; conditioning compositions comprising 3-MPA and citric acid and/or maleic acid; and, optionally, a composition or an agent for altering the color or shape of the hair.
[0019] According to various embodiments, hair care kits may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid; and a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid.
[0020] In further embodiments, hair treatment or hair color change kits may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid, and optionally a composition or an agent to change hair color; and a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid. In still other embodiments, hair treatment or hair color altering kits may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid; a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid; and one or more additional compartments containing one or more agents or one or more hair color altering compositions.
[0021] In further embodiments, hair care or hair shaping kits may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid, and optionally a composition or an agent to change the shape of the hair; and a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid. In still other embodiments, hair care or hair shaping kits may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid; and a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid; and one or more additional compartments containing one or more agents or one or more hair shaping agents or compositions.
[0022] In additional embodiments, kits for hair treatment or for changing the color or shape of hair may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid chosen from maleic acid, citric acid, and combinations thereof, and optionally a composition or agent for altering the color or shape of hair; and a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid. In still other embodiments, kits for treating hair or for changing the color or shape of hair may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid chosen from maleic acid, citric acid , and combinations thereof; a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid selected from maleic acid, citric acid, and combinations thereof; and one or more additional compartments containing one or more agents or one or more compositions for altering the color or shape of hair.
[0023] In still other embodiments, kits for hair treatment or for changing the color or shape of hair may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid chosen from maleic acid , citric acid, and combinations thereof, and optionally a composition or agent for altering the color or shape of hair; and a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid selected from maleic acid, citric acid, and combinations thereof. In still other embodiments, kits for treating hair or for changing the color or shape of hair may comprise: a first compartment containing a treatment composition comprising at least one monoamine and at least one carboxylic acid chosen from maleic acid, citric acid , and combinations thereof; a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid selected from maleic acid, citric acid, and combinations thereof; and one or more additional compartments containing one or more agents or one or more compositions for altering the color or shape of hair. BRIEF DESCRIPTION OF THE DRAWINGS
[0024] The present description and claims can be better understood from the following detailed description either alone or together with the attached drawings. The drawings are included to provide further understanding, and are incorporated in, and form part of, this descriptive report. The drawings illustrate one or more exemplary embodiments of the present description and together with the description serve to explain various principles and operations.
[0025] Figures 1 to 5 show sensory data comparing strength and tactile substance relative to hair samples treated with a bleaching composition containing a hair treatment composition according to an embodiment of the description containing a monoamine and carboxylic acid in relative to hair samples treated with monoamine alone, pH adjusted monoamine, carboxylic acid alone, and pH adjusted carboxylic acid, with baseline (0) being the standard hair bleach formulation without additive.
[0026] Figure 1 shows the sensory comparison in relation to 3-MPA and citric acid.
[0027] Figure 2 shows the sensory comparison in relation to 3-MPA and malonic acid.
[0028] Figure 3 shows the sensory comparison in relation to 3-MPA and malic acid.
[0029] Figure 4 shows the sensory comparison in relation to 3-MPA and maleic acid.
[0030] Figure 5 shows the sensory comparison in relation to 3-MPA and oxalic acid. DETAILED DESCRIPTION
[0031] Except in the operational examples, or where otherwise indicated, all numbers expressing amounts of ingredients and/or reaction conditions are to be understood as being modified in all cases by the term "about" which may encompass ± 10 %, ± 8%, ± 6%, ±_5%, ± 4%, ± 3%, ± 2%, ± 1%, or ± 0.5%.
[0032] All numbers expressing pH values are to be understood as being modified in all cases by the term "about" which encompasses up to ± 3%.
[0033] "At least one", as used herein, means one or more and therefore includes individual components, and mixtures and/or combinations as well.
[0034] A "chemical treatment" composition as described herein may include any composition for chemically treating hair, such as by way of non-limiting example, permanent curl, relaxation, straightening, oxidative dyeing, coloring and bleaching (eg, bleaching , lights effect). The terms "chemical treatment composition", "color altering composition", and "format altering composition", and also variations thereof, may be used interchangeably herein without limitation.
"Systems", as used herein, means comprising compositions for treatment in accordance with the description and conditioning compositions in accordance with the description.
[0036] The term "color change" or "color change" as used herein may refer to "lifting" or lightening the color of hair. It can also refer to dyeing or coloring the hair or deposition of dye on the hair. In certain cases, it refers to “lifting” or lightening the hair color and the deposition of dye on the hair in a treatment.
[0037] The term "strength", as used herein, may refer to the strength of the hair fiber with respect to the ease or difficulty of breaking a hair fiber, or the amount of effort or force required to break the fiber when is subjected to a pulling, pulling, stretching, or brushing action.
[0038] The term "protection" as used herein may refer to preventing, minimizing, or reducing damage or additional damage to the hair.
"Hydrocarbons" as used herein include alkanes, alkenes, and alkynes, the alkanes comprising at least one carbon, and the alkenes and alkynes each comprising at least two carbons; it further being that the hydrocarbons may be chosen from linear hydrocarbons, branched hydrocarbons, and cyclic hydrocarbons; wherein additionally the hydrocarbons may be optionally substituted; and wherein in addition the hydrocarbons may optionally further comprise at least one heteroatom intercalated in the hydrocarbon chain.
"Substituted", as used herein, means comprising at least one substituent. Non-limiting examples of substituents include atoms such as oxygen atoms and nitrogen atoms, and also functional groups such as hydroxyl groups, ether groups, alkoxy groups, acyloxyalkyl groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide group, halogen containing groups, ester groups, thiol groups, sulfonate groups, thiosulfate groups, siloxane groups, and polysiloxane groups. The substituent(s) may be further substituted.
[0041] "Polymers", as defined herein, include homopolymers and copolymers formed from at least two different types of monomers.
[0042] "(Met)acrylic", as used herein, is understood to mean, within the meaning of the present application, "acrylic or methacrylic".
The term "neutralized" as used herein is intended to mean that the at least one monoamine is protonated with an H+ (proton) from the carboxylic acid(s).
[0044] The term "substantially free from (a component)", as defined herein, means that the system or composition contains no appreciable amount of the component, for example, not more than about 1% by weight, not more than 0 .5% by weight, or no more than about 0.3% by weight, such as no more than about 0.1% by weight, based on the weight of the composition.
[0045] The term "free or completely free from (a component)", as defined herein, means that the composition does not contain the component to any degree measurable by standard means.
[0046] As used herein, a carboxylic acid is described as being present in a composition irrespective of whether the carboxylic acid is present in acidic form or whether the acid is dissociated or forms a salt thereof, eg, upon mixing with a solution or other formulation. Accordingly, whether a composition (eg, a treatment composition, a conditioning composition, or a composition for altering the color or shape of hair) is described herein as comprising an acid, or comprising a certain amount of an acid, but the acid is dissociated or forms a salt in the composition, the description is intended to refer to the acid or the amount thereof present prior to dissociation or salt formation. By way of example only, if a treatment composition comprising at least one monoamine and maleic acid is mixed with a liquid hair bleach composition, and in the hair bleach composition the maleic acid forms a maleic acid salt such that none or substantially no maleic acid is present in the mixture, any reference to the hair bleach composition comprising maleic acid or a specific amount of maleic acid is intended to refer to maleic acid or the amount thereof present in the treatment composition before it is mixed with the hair bleach composition. TREATMENT COMPOSITIONS
[0047] As described herein, the description refers to compositions for treatment comprising at least one monoamine and at least one carboxylic acid. Treatment compositions may additionally comprise additional components such as solvents. In one embodiment, the treatment composition consists essentially of one or more monoamines, one or more carboxylic acids, and one or more solvents. In another embodiment, the composition for treatment consists essentially of monoamine, one or more carboxylic acids, one or more solvents, and one or more coloring agents. In yet another embodiment, the composition for treatment consists of monoamine, one or more carboxylic acids, and one or more solvents. In yet a further embodiment, the composition for treatment consists of monoamine, one or more carboxylic acids, one or more solvents, and one or more coloring agents. Monoamines
[0048] The at least one monoamine can be chosen from any monoamine having the formula R-CH2-NH2. By way of non-limiting example, monoamines useful in various embodiments include 3-isopropoxypropylamine, 3-methoxypropylamine (3-MPA), tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)propylamine , 2-(2-aminoethoxy)ethanol (2-2AEE), 3-butoxypropylamine (3-BPA), and monoethanolamine (MEA), and combinations thereof. In certain embodiments, the at least one monoamine is chosen from combinations of at least two monoamines.
[0049] The at least one monoamine may be present in the composition for treatment in an amount of up to about 20%, such as up to about 19%, up to about 18%, up to about 17%, up to about 16%, up to about 15%, up to about 14%, up to about 13%, up to about 12%, up to about 11%, up to about 10%, up to about 9%, up to about 8%, up to about from 7%, up to about 6%, up to about 5%, up to about 4%, up to about 3%, up to about 2%, up to about 1%, up to about 0.5%, or even about 0.1% by weight, based on the weight of the treatment composition. By way of non-limiting example only, the at least one monoamine may be present in an amount ranging from about 0.0001% to about 20%, such as from about 0.001% to about 15%, from about 0 0.01% to about 12%, or from about 0.1% to about 10% by weight, based on the weight of the treatment composition. In one embodiment, the at least one monoamine can be present in an amount ranging from about 1% to about 15%, such as from about 3% to about 13%, from about 5% to about 11% , from about 6% to about 10%, from about 7% to about 9%, or from about 8% to about 9%, such as from about 1%, from about 2%, from about 3%, about 4%, about 5%, about 6%, about 7%, about 8%, about 9%, about 10%, about 11 %, about 12%, about 13%, about 14%, or about 15% by weight, based on the weight of the treatment composition. It should be understood that when more than one monoamine is present, the total amount of monoamines may be present in these amounts. carboxylic acids
[0050] The compositions for treatment, according to the description, can comprise at least one carboxylic acid. According to the description, useful carboxylic acids include organic compounds that include, for example, one, two, three, or more carboxylic acid (COOH) functional groups and at least one carbon atom.
[0051] In certain exemplary, non-limiting embodiments, the at least one carboxylic acid can be chosen from saturated or unsaturated, substituted or unsubstituted dicarboxylic acids, salts thereof, and mixtures thereof. By way of non-limiting example, the at least one carboxylic acid can be chosen from among dicarboxylic acids of the following formula:
wherein: -R is a C1-C100 cyclic or acyclic hydrocarbon moiety, saturated or unsaturated, linear or branched, comprising from 0 to 30 double and/or triple bonds and/or from 0 to 10 rings, and optionally interrupted by 1 to 30 heteroatoms chosen from O, N and S, and optionally substituted with 1 to 30 substituents chosen from a hydrogen atom, a hydroxyl moiety (-OH), an amino moiety (-NH2), an alkyl (C1 -C30)amino moiety , a poly(C 1 -C 30 )alkylamino portion, a hydroxy(C 1 -C 30 )alkylamino portion, a polyhydroxy(C 1 -C 30 )alkylamino portion, a C 6 -C 30 aryl portion, and in some embodiments -R may be omitted; and -X and X' independently denote a hydrogen atom, an ammonium ion, an alkali metal ion such as Li, Na, K, or an alkaline earth metal such as Be, Mg, Ca or an ion derived from an organic amine as an alkylamine.
[0052] It is understood that the term cyclic hydrocarbon portion for the purposes of the present application is understood to mean a hydrocarbon portion consisting of one or more rings or comprising one or more rings that are pendant or on the main chain, it being possible for the rings to be saturated or unsaturated and are substituted with one or more C1-C30 alkyl or alkenyl or hydroxyl or amino moieties.
[0053] By way of non-limiting example only, useful carboxylic acids may include oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, maleic acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and also combinations thereof. In at least one embodiment, the conditioning composition comprises maleic acid and/or citric acid and optionally at least one additional carboxylic acid. In further embodiments, the composition for treatment comprises at least one carboxylic acid other than maleic acid. In still other embodiments, the treatment composition is free or substantially free of maleic acid.
[0054] The at least one carboxylic acid may be present in the composition for treatment in an amount of up to about 50%, such as up to about 45%, up to about 40%, up to about 35%, up to about 30% , up to about 29%, up to about 28%, up to about 27%, up to about 26%, up to about 25%, up to about 24%, up to about 23%, up to about 22%, up to up to about 21%, up to about 20%, up to about 19%, up to about 18%, up to about 17%, up to about 16%, up to about 15%, up to about 14%, up to about from 13%, up to about 12%, up to about 11%, up to about 10%, up to about 9%, up to about 8%, up to about 7%, up to about 6%, up to about 5 %, up to about 4%, up to about 3%, up to about 2%, up to about 1%, up to about 0.5%, or up to about 0.1% by weight, based on the weight of the composition for treatment. By way of non-limiting example only, the at least one carboxylic acid may be present in an amount ranging from about 0.01% to about 30%, such as from about 0.1% to about 28%, of from about 1% to about 26%, or from about 3% to about 25% by weight, based on the weight of the treatment composition. In an exemplary embodiment, the at least one carboxylic acid can be present in an amount in the range of from about 5% to about 25%, such as from about 5% to about 15%, from about 8% to about 12%, or from about 10% to about 11% by weight, based on the weight of the treatment composition. In another exemplary embodiment, the at least one carboxylic acid can be present in an amount in the range of from about 20% to about 35%, such as from about 20% to about 30%, from about 22% to about from 28%, or from about 23% to about 25% by weight, based on the weight of the treatment composition. For example, the at least one carboxylic acid can be present in an amount of from about 10% to about 25%, such as from about 5%, from about 6%, from about 7%, from about 8% , of about 9%, of about 10%, of about 11%, of about 12%, of about 13%, of about 14%, of about 15%, of about 16%, of about 17%, about 18%, about 19%, about 20%, about 21%, about 22%, about 23%, about 24%, about 25%, about 26%, about 27%, about 28%, about 29%, or about 30%, by weight, based on the weight of the treatment composition. It should be understood that when more than one carboxylic acid is present, the total amount of carboxylic acids may be present in these amounts. Solvent
The composition for treatment may additionally comprise at least one solvent. In various exemplary and non-limiting embodiments, the solvent may be chosen from cosmetically acceptable solvents chosen from water, at least one cosmetically acceptable organic solvent, and mixtures thereof.
[0056] Organic solvents can be volatile or non-volatile compounds. As examples of organic solvents, non-limiting examples include monoalcohols and polyols such as ethanol, isopropyl alcohol, propyl alcohol, benzyl alcohol, and phenylethanol, or glycols or glycol ethers such as, for example, monomethyl, monoethyl and monobutyl ethers of ethylene glycol, glycol propylene or ethers thereof such as, for example, propylene glycol, butyl glycol, hexylene glycol monomethyl ether, dipropylene glycol, and also alkyl ethers of diethylene glycol, for example monomethyl ether or diethylene glycol monobutyl ether.
[0057] Other suitable examples of organic solvents are ethylenic glycol, propylene glycol, butylenic glycol, hexylene glycol, propanediol, and glycerin.
[0058] The cosmetically acceptable solvent may comprise an amount in the range of up to about 95%, such as up to about 90%, up to about 85%, up to about 80%, up to about 75%, up to about 70% , up to about 65%, up to about 60%, up to about 55%, or up to about 50%, by weight, based on the weight of the treatment composition. For example, the cosmetically acceptable solvent can range from about 65% to about 95% by weight, from about 70% to about 90% by weight, or from about 80% to about 85% by weight. , or from about 5% to about 20% by weight, based on the weight of the treatment composition.
[0059] Additional components may optionally be present in the composition for treatment. By way of example only, the treatment composition may comprise coloring agents (including but not limited to permanent, demi-permanent, or semi-permanent hair coloring agents), pH adjusters, emulsifiers, thickening agents and rheology modifying agents, cationic polymers, wetting agents and moisturizing agents, chelating agents such as glycine, emulsifying agents, fillers, structuring agents, propellants, anionic surfactants, cationic surfactants, amphoteric surfactants, brightening agents, conditioning agents, and reinforcing agents.
The pH of the composition for treatment can range from up to about 7, such as from about 1 to about 6, from about 1 to about 4, such as from about 2 to about 4, from about from 2.5 to about 3.5, or from about 2 to about 3.
The treatment composition can, in various embodiments, be applied to the hair within about 24 hours, such as less than 24 hours or less than 12 hours, before or after the color change composition. In at least certain exemplary embodiments, the treatment composition can be applied to the hair within a few hours or a few minutes before or after the color altering composition. For example, the treatment composition can be applied within about 1 to about 6 hours before or after the treatment composition [sic], or it can be applied up to about 60 minutes, such as up to about 30 minutes , up to about 20 minutes, up to about 10 minutes, up to about 5 minutes, up to about 2 minutes, or up to about 1 minute before or after the color change composition.
In yet other embodiments, the treatment composition may be applied to the hair at the same time or substantially at the same time as the color or shape change composition. For example, the treatment composition can be mixed with the color or shape change composition, or it can be applied simultaneously with the color or shape change composition. In various exemplary embodiments in which the treatment composition is mixed with the color or shape altering composition, the pH of the resulting mixture can be in the range, for example, from about 7 to about 12, such as from about 8 to about 11, from about 9 to about 11, or from about 10 to about 11.
[0063] In still other embodiments, the treatment composition can be applied to the hair within about 24 hours, such as less than 24 hours or less than 12 hours, before or after a composition that is not a change composition. the color or shape of the hair. In at least certain exemplary embodiments, the treatment composition can be applied to the hair within a few hours or a few minutes before or after the composition that is not a hair color or shape change composition. For example, the treatment composition can be applied within about 1 to about 6 hours before or after the composition that is not a hair color or shape change composition, or it can be applied up to about 60 minutes, such as up to about 30 minutes, up to about 20 minutes, up to about 10 minutes, up to about 5 minutes, up to about 2 minutes, or up to about 1 minute before or after the composition other than is a composition for changing the color or shape of hair.
In yet other embodiments, the treatment composition may be applied to the hair at the same time or substantially the same time as a hair treatment composition that is not a color or shape change composition. For example, the treatment composition can be mixed with a composition that is not a hair color or shape change composition, or it can be applied simultaneously with a hair treatment composition. In yet another embodiment, the treatment composition can be mixed with water and applied to the hair.
[0065] In yet another embodiment, the treatment composition may be mixed with water and applied to the hair.
The composition for treatment can be left on the hair for a period of time in the range of up to one hour, such as from about 3 minutes to about 45 minutes, from about 5 minutes to about 30 minutes, or from about 5 minutes to about 30 minutes. about 10 minutes to about 20 minutes. In additional embodiments, the treatment composition may be left on the hair for a period of up to 30 minutes, such as from about 1 to about 30 minutes, from about 1 to about 10 minutes, or from about 1 to about 10 minutes. from 1 to about 5 minutes. Exemplary component combinations and quantities
[0067] According to various embodiments, the composition for treatment can include at least one monoamine and a combination of carboxylic acids. By way of non-limiting example, the composition for treatment may include at least one monoamine and a combination of two carboxylic acids, such as malonic acid and citric acid, malonic acid and oxalic acid, malonic acid and maleic acid, malonic acid and malic acid, citric acid and oxalic acid, citric acid and maleic acid, citric acid and malic acid, oxalic acid and maleic acid, oxalic acid and malic acid, maleic acid and malic acid, and so on. In additional embodiments, the composition for treatment can include at least one monoamine and combinations of three or more carboxylic acids.
In some embodiments, the composition for treatment can include at least one monoamine and one or more saturated carboxylic acids, and can be free or substantially free of unsaturated carboxylic acids. In some embodiments, the composition for treatment can include at least one monoamine and one or more unsaturated carboxylic acids, and can be free or substantially free of saturated carboxylic acids. In still other embodiments, the composition for treatment can include at least one monoamine and both saturated carboxylic acids (eg, oxalic acid, malonic acid, glutaric acid, succinic acid, adipic acid, glycolic acid, citric acid, tartaric acid, malic acid, sebacic acid, glyoxylic acid monohydrate) or unsaturated carboxylic acids (maleic acid, fumaric acid, benzoic acid, citraconic acid).
In one embodiment, the composition for treatment may include from about 2% by weight to about 14% by weight of monoamine. For example, when the composition for treatment includes 3-methoxypropylamine (3-MPA), the composition may include from about 3% by weight to about 13% by weight, from about 4% by weight to about 12% by weight. weight, from about 5% by weight to about 11% by weight, from about 6% by weight to about 10% by weight, from about 7% by weight to about 9% by weight, or about 8% by weight of 3-MPA, based on the total weight of the treatment composition.
In various embodiments, the composition for treatment can include from about 5% by weight to about 30% by weight of carboxylic acid, such as from about 10% by weight to about 25% by weight, from about 9% by weight to about 11% by weight, or from about 23% by weight to about 25% by weight carboxylic acid.
In various exemplary embodiments, the composition for treatment can include from about 20% by weight to about 30% by weight of citric acid. For example, the composition for treatment can include from about 21% by weight to about 29% by weight, from about 22% by weight to about 28% by weight, from about 23% by weight to about 27. % by weight, from about 24% by weight to about 25% by weight, or about 24.5% by weight citric acid, based on the total weight of the treatment composition.
In other exemplary embodiments, the composition for treatment can include from about 1% by weight to about 15% by weight of maleic acid. For example, the composition for treatment may include from about 5% by weight to about 15% by weight, from about 7% by weight to about 13% by weight, from about 9% by weight to about 11 wt. % by weight, or from about 10% by weight to about 11% by weight maleic acid, based on the total weight of the treatment composition.
By way of non-limiting example only, the composition for treatment may include from about 7% by weight to about 9% by weight of 3MPA, and from about 10% by weight to about 30% by weight of carboxylic acids, such as from about 7% by weight to about 9% by weight 3-MPA and from about 23% by weight to about 26% by weight citric acid, based on the weight of the treatment composition. In additional embodiments, the composition for treatment can include from about 7% by weight to about 9% by weight of 3-MPA, and from about 5% by weight to about 15% by weight of carboxylic acids, such as from about 7% by weight to about 9% by weight 3-MPA and about 9% by weight to about 11% by weight citric acid, based on the weight of the treatment composition.
According to various embodiments, the composition for treatment can include 3-MPA and a combination of carboxylic acids. For example, the composition for treatment may include malonic acid and citric acid, malonic acid and oxalic acid, malonic acid and maleic acid, malonic acid and malic acid, citric acid and oxalic acid, citric acid and maleic acid, citric acid and malic acid , oxalic acid and maleic acid, oxalic acid and malic acid, maleic acid and malic acid, etc. In additional embodiments, the composition for treatment can include 3-MPa and combinations of three carboxylic acids.
In some embodiments, the composition for treatment may include one or more saturated carboxylic acids and may be substantially free of, or free of, unsaturated carboxylic acids. In some embodiments, the composition for treatment can include one or more unsaturated carboxylic acids and can be substantially free of, or free of, saturated carboxylic acids. In some embodiments, the treatment composition can include both saturated and unsaturated carboxylic acids.
[0076] According to certain embodiments, the total combined amount of monoamine and carboxylic acid present in the composition for treatment can be in the range of up to about 50%, such as from about 0.1% to about 40%, from about from 1% to about 35%, from about 1% to about 30%, from about 2% to about 25%, from about 5% to about 25%, from about 8% to about 23%, from about 12% to about 35%, or about 18% to about 35% by weight, based on the weight of the treatment composition.
[0077] Without intending to limit the description, it may, in various embodiments, be advantageous to choose certain amounts of the monoamine, eg 3-MPA, of at least one carboxylic acid, solvent, and/or optionally any additional component in the composition for treatment , or ratios of the components in relation to one another, for the purpose of providing or improving the synergistic results of combinations thereof. COLOR CHANGING COMPOSITION
Before, after, or simultaneously with the treatment composition, a color altering composition can be applied to the hair. In various exemplary embodiments, the color altering composition can comprise a hair bleaching agent. For example, the color altering composition can be formed by combining, in a cosmetically acceptable carrier, a bleaching composition comprising at least one oxidizing agent chosen from persulfates, perborates, percarbonates, peracids, bromates, their salts and mixtures thereof, and a developer composition comprising hydrogen peroxide. In additional embodiments, the oxidizing agent and developer composition can be separated. In still other embodiments, the color altering composition may comprise at least one coloring compound chosen from oxidative dye precursors, direct dyes, pigments, and mixtures thereof. bleaching agent
[0079] According to various embodiments, the color altering composition may comprise, in a cosmetically acceptable carrier, at least one oxidizing agent chosen from peroxides, persulfates, perborates, percarbonates, peracids, bromates, their salts and mixtures thereof. The at least one oxidizing agent can optionally be water soluble.
[0080] Optional peroxides useful herein include, for example, hydrogen peroxide, magnesium peroxide, PVP-peroxide, calcium peroxide, and sodium peroxide.
[0081] Exemplary, non-limiting persulfates include potassium persulfate, sodium persulfate, and ammonium persulfate. In various embodiments, exemplary oxidizing agents can be chosen from sodium perborate and sodium percarbonate. In additional embodiments, exemplary peracids may be chosen from organic peracids having the general formula (I):
wherein, in formula (I), R is chosen from aryl, alkylaryl or straight or branched chain alkyl, saturated or unsaturated, substituted or unsubstituted groups having from 1 to 22 carbon atoms. In at least some exemplary embodiments, mixtures of two or more oxidizing agents selected from persulfates, perborates, percarbonates, peracids, bromates, and salts thereof may be chosen.
[0082] In various embodiments, the at least one bleaching agent is chosen from alkali metal salts of perborates, percarbonates, bromates, and persulfates, such as, for example, ammonium, sodium, and potassium salts. Discoloring composition
[0083] When the color altering composition comprises separate bleaching and developer compositions, the bleaching composition may comprise at least one oxidizing agent chosen from persulfates, perborates, percarbonates, peracids, bromates, their salts, and mixtures thereof, such as those described above . In various embodiments, the at least one oxidizing agent is chosen from alkali metal salts of perborates, percarbonates, bromates, and persulfates, such as, for example, ammonium, sodium, and potassium salts. The bleaching composition may also optionally comprise a cosmetically acceptable carrier.
[0084] The at least one oxidizing agent of bleaching compositions, according to various modalities of the description, is used in an amount sufficient to lighten or "bleach" the hair. By way of example only, the at least one oxidizing agent of the decolorizing composition may be present in an amount ranging from about 10% by weight to about 100% by weight, such as from about 20% to about 90% by weight. weight, from about 30% to about 80% by weight, or from about 40% to about 75% by weight, based on the weight of the bleach composition. In additional embodiments, the at least one oxidizing agent of the bleaching composition can be present in an amount in the range of from about 5% to about 50%, such as from about 10% to about 45%, or from about 15% at about 40%. In an exemplary embodiment, the at least one oxidizing agent of the bleaching composition can be present in an amount of at least 40% by weight, based on the weight of the bleaching composition.
[0085] The bleaching composition can be in any form, such as, for example, in the form of a powder, gel, liquid, foam, lotion, cream, mousse, and emulsion.
[0086] In various exemplary embodiments, the bleach composition can be anhydrous. Optionally, water can be added as an activator, by mixing it with the bleaching composition.
[0087] The bleaching composition of the present invention may also contain acidic and alkaline pH adjusters, which are well known in the art in the cosmetic treatment of keratin fibers such as hair. Such pH adjusters include, but are not limited to, sodium metasilicate, silicate compounds, citric acid, ascorbic acid, and carbonate compounds.
[0088] The pH adjusters can, in various embodiments, be present in the bleach composition in an amount effective to provide the color altering composition with a pH in the range of about 1 to about 7 when the bleach composition is combined with the revealing composition. By way of example, the amount of pH adjuster can be present, in various embodiments, in an amount of at least about 0.01%, such as at least about 0.1%, at least about 0. 2%, or at least about 0.5%.
[0089] According to an exemplary embodiment, the bleach composition is alkaline, with a pH in the range of about 7, 8, 9 or 10, to about 8, 9, 10, or 11. According to another embodiment By way of example, the bleach composition has a pH higher than about 7.
[0090] When the bleaching composition is in powder form, the pH can be measured in a 1% solution in water.
[0091] Colorants may also optionally be present in the bleaching compositions described herein. Useful colorants, in accordance with various embodiments of the description, are those colorants that are stable in the bleach composition, and can impart additional coloring and coloring to the hair. Exemplary hair dyes include, but are not limited to, pigments, fat-soluble dyes, direct dyes, pearlescent pigments, pearlizing agents, leuco dyes, optical brightening dyes, natural dyes, and optically variable pigments. revealing composition
[0092] When the color change composition comprises separate bleach and developer compositions, the developer composition comprises hydrogen peroxide. The developer composition may also optionally comprise a cosmetically acceptable carrier.
[0093] In various exemplary embodiments, hydrogen peroxide is present in an amount of at least 1% by weight, based on the total weight of the developer composition. In additional embodiments, the hydrogen peroxide is present in an amount ranging from about 0.1% to about 80% by weight, such as from about 1.0% to about 75% by weight, or from about 2% to about 10% by weight, based on the weight of the developer composition. In other exemplary embodiments, hydrogen peroxide may be present in the developer composition in an amount ranging from about 2% to about 25%, such as from about 4% to about 20%, from about 6% to about from 15%, or from about 7% to about 10%.
[0094] The cosmetically acceptable carrier of the developer composition may, for example, be present in an amount ranging from about 0.5% to about 99% by weight, such as from about 5% to about 95% by weight , in relation to the total weight of the developer composition.
[0095] The pH of the developer composition can range from about 1 to about 5, such as from about 2 to about 4, and can be adjusted to the desired value using pH adjusters that are well known in the art in the cosmetic treatment of keratin fibers, including, for example, those described herein.
[0096] The developer composition can be in any form, such as, for example, in the form of a powder, gel, liquid, foam, lotion, cream, mousse, and emulsion.
[0097] According to various exemplary embodiments, the developer composition can be anhydrous. Optionally, water can be added as an activator, by mixing it with the developer composition.
[0098] The developer composition can, in various modalities, comprise additional components such as, for example, at least one auxiliary ingredient chosen from rheology modifying agents, chelating agents, fatty substances, ceramides, alkoxyaminosilicones, and silanes, and any other known component in the art as being useful in a revealing composition.
In at least one exemplary embodiment, the bleach composition can be mixed with the developer composition to form the color changing composition immediately prior to (e.g., within a few minutes prior to) applying the color changing composition to the hair.
[00100] In an exemplary embodiment, the bleaching composition and the developing composition can be combined to form the bleaching composition in a ratio of the bleaching composition to the developing composition in the range of from about 1:1 to about 1:5, such as from about 1:1 to about 1:2, or about 1:2 to about 1:4. Coloring compounds
[00101] As described herein, in various exemplary and non-limiting embodiments, color altering compositions may optionally comprise at least one coloring compound chosen from oxidative dyes, direct dyes, pigments, and mixtures thereof.
[00102] Oxidative dyes are, in general, chosen from one or more oxidative bases optionally combined with one or more couplers.
[00103] By way of example, the oxidative bases can be chosen among para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols and heterocyclic bases, and the addition salts thereof.
[00104] Among the para-phenylenediamines that may be mentioned are, for example, para-phenylenediamine, para-toluenediamine, 2-chloro-para-phenylenediamine, phenylenediamine, phenylenediamine, phenylenediamine, methylaniline, hydroxyethyl)amino-2-methylaniline, chloroaniline, 2-β-hydroxyethyl-para-phenylenediamine, phenylenediamine, 2-fluoro-para-phenylenediamine, phenylenediamine, N-(β-hydroxypropyl)-para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N,N-dimethyl- 3-methyl-para-phenylenediamine, N-ethyl-N-(β-hydroxyethyl)-para-phenylenediamine, N-(β,Y-dihydroxypropyl)-para-phenylenediamine, N-(4'-aminophenyl)-para -phenylenediamine, N-phenyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para-phenylenediamine, 2-β-acetylaminoethyloxy-para-phenylenediamine, N-(β-methoxyethyl)-para-phenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl -para-phenylenediamine, 2-β-hydroxyethylamino-5-aminotoluene and 3-hydroxy-1-(4'-aminophenyl)pyrrolidine, and the addition salts thereof with an acid.
[00105] Among the para-phenylenediamines mentioned above, para-phenylenediamine, para-toluenediamine, 2-isopropyl-para-phenylenediamine, 2-β-hydroxyethyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para-phenylenediamine, 2,6 -dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, N,N-bis(β-hydroxyethyl)-para-phenylenediamine, 2-chloro-para-phenylenediamine and 2-β-acetylaminoethyloxy-para-phenylenediamine, and the addition salts thereof with an acid, are particularly preferred.
[00106] Among the bis(phenyl)alkylenediamines that may be mentioned are, for example, N,N'-bis(β-hydroxyethyl)-N,N'-bis(4'-aminophenyl)-1,3-diaminopropanol, N,N'-bis(β-hydroxyethyl)-N,N'-bis(4'-aminophenyl)ethylenediamine, N,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-bis(β-hydroxyethyl) -N,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-bis(4-methylaminophenyl)tetramethylenediamine, N,N'-bis(ethyl)-N,N'-bis(4'-amino-3 '-methylphenyl)ethylenediamine and 1,8-bis(2,5-diaminophenoxy)-3,6-dioxaoctane, and the addition salts thereof.
[00107] Among the para-aminophenols that may be mentioned are, for example, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-amino-3 -hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2-(β-hydroxyethylaminomethyl)phenol and 4- amino-2-fluorophenol, and the addition salts thereof with an acid.
[00108] Among the ortho-aminophenols that may be mentioned are, for example, 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and the addition salts of the same.
[00109] Among the heterocyclic bases that may be mentioned are, for example, pyridine derivatives, pyrimidine derivatives and pyrazol derivatives.
[00110] Among the pyridine derivatives that may be mentioned are the compounds described, for example, in GB patent No. 1,026,978 and GB patent No. 1,153,196, for example 2,5-diaminopyridine, 2-(4 - methoxyphenyl)amino-3-aminopyridine and 3,4-diaminopyridine, and the addition salts thereof.
[00111] Other oxidative pyridine bases can include the oxidative bases 3-aminopyrazolo[1,5-a]pyridine or the addition salts thereof described, for example, in FR patent application No. 2,801,308. Examples which may be mentioned include pyrazolo[1,5-a]pyrid-3-ylamine, 2-acetylaminopyrazolo[1,5-a]pyrid-3-ylamine, 2-morpholin-4-ylpyrazolo[1,5-a] pyrid-3-ylamine, 3-aminopyrazolo[1,5-a]pyridine-2-carboxylic acid, 2-methoxypyrazolo[1,5-a]pyrid-3-ylamine, (3-aminopyrazolo[1,5-a] pyrid-7-yl)methanol, 2-(3-aminopyrazolo[1,5-a]pyrid-5-yl)ethanol, 2-(3-aminopyrazolo[1,5-a]pyrid-7-yl)ethanol, (3-aminopyrazolo[1,5-a]pyrid-2-yl)methanol, 3,6-diaminopyrazolo[1,5-a]pyridine, 3,4-diaminopyrazolo[1,5-a]pyridine, pyrazolo[1 ,5-a]pyridine-3,7-diamine, 7-morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine, pyrazolo[1,5-a]pyridine-3,5-diamine, 5 -morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine, 2-[(3-aminopyrazolo[1,5-a]pyrid-5-yl)(2-hydroxyethyl)amino]ethanol, 2- [(3-aminopyrazolo[1,5-a]pyrid-7-yl)(2-hydroxyethyl)amino]ethanol, 3-aminopyrazolo[1,5-a]pyridin-5-ol, 3-aminopyrazolo[1,5 -a]pyridin-4-ol, 3-aminopyrazolo[1,5-a]pyridin-6-ol, 3-aminopyrazolo[1,5-a]pyridin-7-ol, 2-□-hydroxyethoxy-3-amino -pyrazolo[1, 5-a]pyridine; 2-(4-dimethylpiperazinium-1-yl)-3-amino-pyrazolo[1,5-a]pyridine; and the addition salts thereof.
[00112] More particularly, the oxidative bases can be selected from 3-aminopyrazolo-[1,5-a]-pyridines and are preferably substituted on the 2nd carbon atom with: (a) a (di)(alkyl) group )(C1-C6)amino in which said alkyl group may be substituted with at least one hydroxyl, amino, imidazolium group; (b) a heterocycloalkyl group containing 5 to 7 chain members and 1 to 3 heteroatoms, potentially cationic, potentially substituted with one or more (C1-C6) alkyls, such as di(C1-C4)alkylpiperazinium; or (c) a (C 1 -C 6 )alkoxy potentially substituted with one or more hydroxy groups such as α-hydroxyalkoxy, and the addition salts thereof.
[00113] Among the pyrimidine derivatives that may be mentioned are the compounds described, for example, in patent nos. DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or in patent application no. WO 96/15765, as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2 ,4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and their tautomeric forms, when a tautomeric equilibrium exists.
Among the pyrazole derivatives that may be mentioned are the compounds described in patent nos. DE 3843892, DE 4133957 and in patent application nos. WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 19543988, as 4,5-diamino-1-methylpyrazole, 4,5-diamino-1-(β-hydroxyethyl)pyrazole, 3,4-diaminopyrazole, 4,5-diamino-1-(4'-chlorobenzyl )pyrazole, 4,5-diamino-1,3-dimethylpyrazole, 4,5-diamino-3-methyl-1-phenylpyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3 -dimethyl-5-hydrazinopyrazole, 1-benzyl-4,5-diamino-3-methylpyrazole, 4,5-diamino-3-tert-butyl-1-methylpyrazole, 4,5-diamino-1-tert-butyl-3 -methylpyrazole, 4,5-diamino-1-(β-hydroxyethyl)-3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3-(4' - methoxyphenyl)pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethylpyrazole, 4,5-diamino-3-hydroxymethyl-1-methylpyrazole, 4,5-diamino-3-hydroxymethyl-1-isopyrazole, 4,5 - diamino-3-methyl-1-isopropylpyrazole, 4-amino-5-(2'-aminoethyl)amino-1,3-dimethylpyrazole, 3,4,5-triaminopyrazole, 1-methyl-3,4,5-tr iaminopyrazole, 3,5-diamino-1-methyl-4-methylaminopyrazole, 3,5-diamino-4-(β-hydroxyethyl)amino-1-methylpyrazole, and the addition salts thereof. 4,5-Diamino-1-(β-methoxyethyl)pyrazole can also be used.
[00115] A 4,5-diaminopyrazole will preferably be used, and even more preferably 4,5-diamino-1-(β-hydroxyethyl)pyrazole and/or a salt thereof.
[00116] The pyrazole derivatives which may also be mentioned include diamino-N,N-dihydropyrazolopyrazolones and especially those described in patent application no. FR-A-288636, as the following compounds and the addition salts thereof: 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H, 5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-isopropylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-(pyrrolidin-1-yl)-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 4,5-diamino-1,2- dimethyl-1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-diethyl-1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl)-1,2-dihydropyrazol-3-one, 2-amino-3-(2-hydroxyethyl)amino-6,7-dihydro-1H,5H-pyrazolo[1,2-a ]pyrazol-1-one, 2-amino-3-dimethylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2,3-diamino-5,6 ,7,8-tetrahydro-1H,6H-pyridazino[1,2-a]pyrazol-1-one, 4-amino-1,2-diethyl-5-(pyrrolidin-1-yl)-1,2 -dihydropyrazol-3-one, 4-amino-5-(3-d imethylaminopyrrolidin-1-yl)-1,2-diethyl-1,2-dihydropyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H,5H-pyrazolo[1 ,2-a]pyrazol-1-one.
[00117] 2,3-Diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and/or a salt thereof will preferably be used.
[00118] 4,5-Diamino-1-(β-hydroxyethyl)pyrazole and/or 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1- One and/or a salt thereof will preferably be used as heterocyclic bases.
[00119] The compositions may further optionally comprise one or more couplers advantageously chosen from those conventionally used in dyeing or coloring keratinous substrates.
[00120] Among these couplers, mention can be made especially to meta-phenylenediamines, meta-aminophenols, meta-diphenols, couplers based on naphthalene and heterocyclic couplers, and also the addition salts thereof.
[00121] Mention may be made, for example, of 2-methyl-5-aminophenol, 5-N-(β-hydroxyethyl)amino-2-methylphenol, 3-aminophenol, 5-amino-6-chloro-o-cresol (3-amino-2-chloro-6-methylphenol), 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 2,4- diamino-1-(β-hydroxyethyloxy)benzene, 2-amino-4-(β-hydroxyethylamino)-1-methoxybenzene, 1,3-diaminobenzene, 1,3-bis(2,4-diaminophenoxy)propane, 3-ureidoaniline , 3-ureido-1-dimethylaminobenzene, sesamol, 1-β-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole , 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3,5-diamino-2,6-dimethoxypyridine, 1-N-(β-hydroxyethyl)amino-3,4-methylenedioxybenzene, 2,6-bis(β- hydroxyethylamino) toluene, 6-hydroxyindoline, 2,6-dihydroxy-4-methylpyridine, 1-H-3-methylpyrazol-5-one, 1-phenyl-3-methylpyrazol-5-one, 2,6-dimethylpyrazolo[ 1,5-b]-1,2,4-triazole, 2,6-dimethyl[3,2-c]-1,2,4-triazole and 6-methylpyrazolo[1,5-a]benzimidazo l, the addition salts thereof with an acid, and mixtures thereof.
[00122] In general, addition salts of oxidative bases and couplers that can be used are chosen from addition salts with an acid such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
[00123] The oxidative base(s) may be present in an amount ranging from about 0.001% to 10% by weight, such as from about 0.005% to 5% in weight, with respect to the total weight of the composition comprising the system in which it(s) is(are) present.
[00124] The coupler(s), if present, may be present in an amount in the range of from about 0.001% to 10% by weight, such as about from 0.005% to 5% by weight, relative to the total weight of the system or composition comprising the system in which it(s) is(are) present.
[00125] The compositions according to the modalities of the description may optionally comprise one or more direct natural or synthetic dyes, for example chosen from anionic and non-ionic species, preferably cationic or non-ionic species, either as dyes alone or in addition to the oxidative dye(s).
[00126] Examples of suitable direct dyes which may be mentioned include azoic direct dyes; (poly)methic dyes such as cyanines, hemicyanins and styrils; carbonyl dyes; azine dyes; nitro(hetero)aryl dyes; tri(hetero)arylmethane dyes; porphyrin dyes; phthalocyanine dyes; and natural direct dyes, alone or as mixtures.
[00127] Direct dyes are preferably cationic direct dyes. Mention can be made to the cationic hydrazone dyes of formulas (Va) and (V'a), to the azoic cationic dyes (VIa) and (VI'a) to the diazoic cationic dyes (VIIa) below:
in whose formulas (Va), (V'a), (VIa), (VI'a) and (VIIa): • Het+ represents a cationic heteroaryl moiety, preferably having an endocyclic cationic charge, such as imidazolium, indole or pyridinium, optionally substituted preferably with one or more (C 1 -C 8 )alkyl groups such as methyl; Ar+ represents an aryl moiety, such as phenyl or naphthyl, having an exocyclic cationic charge, preferably ammonium, particularly trialkyl(C1-C8)ammonium such as trimethylammonium; Ar represents an aryl group, especially phenyl, which is optionally substituted, preferably with one or more electron donating groups such as i) optionally substituted (C 1 -C 8 )alkyl, ii) optionally substituted (C 1 -C 8 )alkoxy, iii) (di )(C1-C8)alkylamino optionally substituted on the alkyl group(s) with a hydroxyl group, iv) aryl-(C1-C8)alkylamino, v) N-(C1-C8)alkyl-N -aryl(C 1 -C 8 )alkylamino optionally substituted or alternatively Ar represents a julolidine group; Ar' is an optionally substituted divalent (hetero)arylene group such as phenylene, particularly para-phenylene, or naphthalene, which are optionally substituted, preferably with one or more (C 1 -C 8 )alkyl, hydroxy or (C 1 -C 8 )alkoxy groups; Ar'' is an optionally substituted (hetero)aryl group such as phenyl or pyrazolyl, which are optionally substituted, preferably with one or more (C1-C8) alkyl, hydroxyl, (di)(C1-C8) alkylamino, groups, (C 1 -C 8 )alkoxy or phenyl; Ra and Rb, which can be identical or different, represent a hydrogen atom or a (C1-C8) alkyl group, which is optionally substituted, preferably with a hydroxyl group; or alternatively the Ra with a Het+ and/or Rb with an Ar and/or Ra with Rb substituent form, together with the atoms having, a (hetero)cycloalkyl; particularly, Ra and Rb represent a hydrogen atom or a (C 1 -C 4 )alkyl group, which is optionally substituted by a hydroxyl group; • An- represents an anionic counterion such as mesylate or halide.
[00128] In particular, mention can be made of cationic azo dyes and hydrazone having an endocyclic cationic charge of the formulas (Va), (V’a) and (VIa) as defined above. Mention may be made more particularly of those of formulas (Va), (V'a) and (VIa) derived from the dyes described in patent applications Nos. WO 95/15144, WO 95/01772 and EP-714954.
[00129] In various embodiments, the cationic part is derived from the following derivatives:
- R 1 represents a (C 1 -C 4 )alkyl group such as methyl; - R2and R3, which are identical or different, represent a hydrogen atom or a (C1-C4)alkyl group, such as methyl; and - R 4 represents a hydrogen atom or an electron donating group such as optionally substituted (C 1 -C 8 )alkyl, optionally substituted (C 1 -C 8 ) alkoxy, or (di)(C 1 -C 8 alkyl)amino optionally substituted in the(s) ) alkyl group(s) having a hydroxyl group; particularly, R4 is a hydrogen atom, - Z represents a CH group or a nitrogen atom, preferably CH; - An- represents an anionic counterion such as mesylate or halide.
[00130] The colorant of the formulas (Va-1) and (VIa-1) can be chosen from Basic Red 51, Basic Yellow 87 and Basic Orange 31 or derivatives thereof:


[00131] Among the natural direct dyes, mention can be made to lawsone (2-hydroxy-1,4-naphthoquinone), juglone, alizarin, glitter, carminic acid, kermesic acid, purpurogaline, protocatechaldehyde, indigo, isatin, curcumin, spinulosin , apigenidin and orceins Extracts or decoctions containing these natural dyes and in particular henna-based extracts or poultices can also be used.
[00132] When present, the one or more direct dyes more particularly represent from about 0.001% to 10% by weight, such as from about 0.005% to 5% by weight, of the total weight of the system or composition comprising the system in which he(s) is(are) present.
[00133] The color altering composition may also comprise a cosmetically acceptable carrier. The cosmetically acceptable carrier may, for example, be present in the color changing composition in an amount ranging from about 1% to about 40% by weight, such as from about 5% to about 35% by weight, or from about 10% to about 30% by weight of the color change composition.
[00134] Auxiliary ingredients can be added to the color altering composition. Exemplary auxiliary ingredients useful in the color change composition according to various embodiments of the description include, but are not limited to, rheology modifying agents, bleach activators and bleach co-activators, direct dyes, chelators, fatty substances, ceramides, alkoxyaminosilicones, silanes, and lift enhancing agents such as nitrogen-containing compounds and metal catalyst compounds.
[00135] The color altering composition may also contain acidic and alkaline pH adjusters, which are well known in the art in the cosmetic treatment of keratin fibers such as hair. Such pH adjusters include, but are not limited to, sodium metasilicate, silicate compounds, citric acid, ascorbic acid, and carbonate compounds.
[00136] The pH adjusters can, in various embodiments, be present in the color changing composition in an amount effective to provide the color changing composition with a pH of no greater than 7, such as a pH in the range of about 1 to about from about 2 to about 6, or from about 3 to about 5. By way of example, the amount of pH adjuster can be present, in various embodiments, in an amount of at least about 0 .01%, such as at least about 0.1%, at least about 0.2%, or at least about 0.5%.
[00137] The color altering composition may, in at least certain modalities, be in a ready-to-use form.
[00138] The color altering composition can, in various embodiments, be applied to the hair within about 24 hours, such as less than 24 hours or less than 12 hours, after the treatment composition. In at least certain exemplary embodiments, the color altering composition can be applied to the hair within a few hours or a few minutes after the treatment composition. For example, the color changing composition can be applied within about 1 to about 6 hours after the treatment composition, or it can be applied up to about 60 minutes, such as up to about 30 minutes, to about 20 minutes, up to about 10 minutes, to about 5 minutes, to about 2 minutes, or up to about 1 minute after the treatment composition.
[00139] The color changing composition can be left on the hair for a sufficient period of time to achieve the desired change in hair tone. For example, the color changing composition can be left on the hair for up to an hour, such as from about 3 minutes to about 45 minutes, from about 5 minutes to about 30 minutes, or from about 10 minutes to about 20 minutes. In additional embodiments, the color altering composition can be left on the hair for a period of up to about 30 minutes, such as from about 1 to about 30 minutes, from about 1 to about 10 minutes, or from about 1 to about 5 minutes. A person skilled in the art, by considering various factors such as the initial and desired hair hue, will be able to determine an adequate amount of time to leave the color altering composition on the hair for the purpose of achieving the desired change in hue of the hair. hair. By way of non-limiting example, various embodiments according to the description can provide a 1 to 4 increase in hair shade height.
[00140] If desired, the color altering composition can optionally be subjected to shampooing and/or rinsed off the hair. FORMAT CHANGING COMPOSITION (STRUCTURING COMPOSITION)
In additional embodiments, a composition for structuring the hair or for changing the shape of the hair can be applied to the hair prior to, after, or simultaneously with the treatment composition. Compositions for altering the shape of hair comprise hair structuring agents and can be any composition for altering the shape of hair, for example compositions comprising one or more agents for straightening, relaxing, and/or structuring (shaping) the hair.
[00142] By way of example, hair structuring agents may optionally be chosen from inorganic hydroxides or organic hydroxides, for example sodium hydroxide, potassium hydroxide, lithium hydroxide, calcium hydroxide, or guanidine hydroxide, or can be chosen from organic amines and other non-hydroxy compounds. In various embodiments, hair relaxing agents can be chosen from thiol compounds such as cysteine, cysteamine, N-substituted cysteamines, alkyl substituted mercaptoacetamides, dimercaptoadipic acid, thioglycerol, thiolactic acid, thioglycolic acid or its salts, (eg, a thioglycolate ), monothioglycolic acid esters such as diol esters of trioglycolic acid, glyceryl monothioglycolate, thiocholine or its salts, aminothiols, and thiols attached to low molecular weight polymers, sulfites such as sodium hyposulfite, and bisulfites such as ammonium or sodium bisulfite.
[00143] Compositions for changing the shape of hair can optionally comprise at least one surfactant, for example amphoteric/zwitterionic surfactants, nonionic surfactants, anionic surfactants, and cationic surfactants. By way of non-limiting example, the at least one surfactant can be present in an amount ranging from about 0.1% to about 5% by weight, such as from about 0.5% to about 3% by weight. , in relation to the total weight of the format change composition.
[00144] Surfactants Amphoteric Exemplary include, for example, lauryl betaine, lauroanfoglicinato, lauroanfopropilsulfonato, lauroanfopropionato, lauroanfocarboxiglicinato, laurilsultano, miristamidopropilbetaína, miristilbetaína, miristoanfoglicinato, miristilpropionato, estearoanfoglicinato, estearoanfopropionato, estearoanfopropilsulfonato, estearilbetaína, cocamidoetilbetaína, cocamidopropyl betaine, cocamidopropyl hidroxissultano, cocamidopropildimetilaminapropionato, cocanfopropionato , and cocoamphopropylsulfonate, and combinations thereof.
Exemplary nonionic surfactants include fatty acid esters and alkoxylated fatty acid esters, particularly ethoxylated, of polyhydric alcohols such as glycerols and sorbitol, for example polyoxyethylene monolaurate, polyoxyethylene monooleate, polyoxyethylene monostearate, sorbitol monolaurate sorbitan trioleate, generally having a degree of ethoxylation from about 20 to about 85; mono- and di-alkanolamides, such as N-acyl-derivatives of mono- and di-ethanolamines, and polyethoxylated mono-alkanolamides such as PEG-14-cocamide; amine oxides such as cocamidopropyldimethylamine oxides, cocobis-2-hydroxyethylamine oxides and lauryldimethylamine oxide; ethoxylated alkanolamides; ethoxylated oils and ethoxylated fats such as ethoxylated lanolins; and ethoxylated alkylphenols, such as nonoxynol, and combinations thereof.
Exemplary anionic surfactants include, alkyl ether carboxylic acids, such as laureth-11-carboxylic acid, the alkali metal, ammonium, or amine salts of alkyl sulfates, alkyl ether sulfates, alpha-olefin sulfonates, dialkylsulfosuccinates, alkylaminoalkylsulfosuccinates, and succinates. each having alkyl or alkenyl groups from about C12 to C18, and combinations thereof. Specific examples include the salts of lauryl sulfates and lauryl ether sulfates, the latter having an average ethoxylation level of 1-3.
quaternium-26, quaternium-52, quaternium-62, quaternium-76-hydrolyzed collagen, quaternium-77, quaternium-78, quaternium-79-hydrolyzed collagen, hydrolyzed quaternium-79-keratin, hydrolyzed quaternium-79-protein hydrolyzed milk, hydrolyzed quaternium-79-silk, hydrolyzed quaternium-79-soy protein, and hydrolyzed quaternium-79-wheat protein, quaternium-80, quaternium-81, quaternium-82, quaternium-83, quaternium-84, and combinations thereof.
Hair styling compositions may further contain at least one additional ingredient typically found in such compositions. Examples of such ingredients include, but are not limited to, acidic and alkaline pH adjusters, chelating agents, swelling agents, solvents, structuring agents such as waxes and polymers, hydrophobic (lipophilic) and hydrophilic gelling agents or thickeners, skin conditioning agents , sunscreen agents (eg, octocrilene, octinoxate, avobenzone), preservatives (eg, sodium citrate, phenoxyethanol, parabens and mixtures thereof), cosmetic active agents and dermatological active agents such as, for example, hydrolyzed peptides, farnesol, bisabolol , phytantriol, aesthetic agents such as essential oils, fragrances, skin sensory agents, opacifiers, aromatic compounds (eg, clover oil, menthol, camphor, eucalyptus oil, and eugenol), foam enhancing agents, and botanical extracts.
The hair structuring (shape changer) composition may also comprise a cosmetically acceptable carrier. The cosmetically acceptable carrier may, for example, be present in the shape-changer composition in an amount ranging from about 1% to about 40% by weight, such as from about 5% to about 35% by weight, or of about 10% to about 30% by weight of the shape change composition.
In various embodiments, the hair structuring composition comprises or is used together with at least one neutralizer, for example an oxidizing agent. Useful exemplary oxidizing agents include peroxides, bromates, and perborates, e.g., hydrogen peroxide, potassium bromate, sodium bromate, and sodium perborate.
The hair structuring composition can, in various modalities, be applied to the hair within about 24 hours, such as less than 24 hours or less than 12 hours, after the treatment composition. In at least certain exemplary embodiments, the hair structuring composition can be applied to the hair within a few hours or a few minutes after the treatment composition. For example, the hair color builder composition can be applied within about 1 to about 6 hours after the treatment composition, or it can be applied up to about 60 minutes, such as up to about 30 minutes, up to about 20 minutes. , up to about 10 minutes, to about 5 minutes, to about 2 minutes, or up to about 1 minute after the treatment composition.
The hair structuring composition can be left on the hair for a period of time sufficient to achieve the desired change in hair shape. For example, the hair builder composition can be left on the hair for up to an hour, such as from about 3 minutes to about 45 minutes, from about 5 minutes to about 30 minutes, or from about 10 minutes to about 20 minutes. In additional embodiments, the hair builder composition can be left on the hair for a period of up to about 30 minutes, such as from about 1 to about 30 minutes, from about 1 to about 10 minutes, or from about 1 to about 5 minutes. A person skilled in the art, by considering various factors such as the initial hair shape and the desired hair shape, will be able to determine an adequate amount of time to leave the shape-altering composition on the hair for the purpose of achieving the change. desired in the shape of the hair.
[00153] If desired, the shape change composition may optionally be subjected to shampooing and/or rinsed off the hair. CONDITIONING COMPOSITION
[00154] After the treatment composition and/or the color changing composition and/or the shape changing composition have been applied to the hair, and optionally subjected to shampooing and/or rinsing off, the hair can be further treated with a conditioning composition comprising at least one monoamine and at least one carboxylic acid. In various exemplary non-limiting embodiments, the monoamine can be neutralized by at least one carboxylic acid. As used herein, the at least one monoamine that is neutralized with the at least one carboxylic acid means that the at least one monoamine is completely neutralized, is substantially completely neutralized, or is partially neutralized. The term "neutralized" means that the at least one monoamine is protonated by H+ (proton) from, but not limited to, acidic sources such as the carboxylic acid(s).
[00155] The at least one monoamine can be chosen from any monoamine that has the formula R-CH2-NH2. By way of non-limiting example, monoamines useful in various embodiments include 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2 -aminoethoxy)ethanol, 3-butoxypropylamine, and monoethanolamine, and combinations thereof. In certain embodiments, the at least one monoamine is chosen from combinations of at least two monoamines.
[00156] In various embodiments, the at least one monoamine may be present in the conditioning composition in an amount of up to about 10%, such as up to about 9%, up to about 8%, up to about 7%, up to about 6%, up to about 5%, up to about 4%, up to about 3%, up to about 2%, up to about 1%, up to about 0.90%, up to about 0.80%, up to about 0.70%, up to about 0.60%, or up to about 0.50%, based on the weight of the conditioning composition. By way of non-limiting example only, the monoamine may be present in an amount in the range of from about 0.1% to about 5%, such as from about 0.2% to about 4%, or from about 0 .5% to about 3% by weight, based on the weight of the conditioning composition. In one embodiment, the monoamine can be present in an amount in the range of about 0.5% to about 1%, and in another embodiment, the monoamine can be present in an amount in the range of about 1% to about 2% by weight, based on the weight of the conditioning composition.
The at least one carboxylic acid useful for the conditioning composition can be any organic compound containing at least one acid functional group and at least one carbon atom, such as the carboxylic acids described above for the treatment composition. Exemplary and non-limiting carboxylic acids that can be used include organic compounds that include, for example, one, two, three, or more carboxylic acid (COOH) functional groups and at least one carbon atom.
[00158] In certain exemplary, non-limiting embodiments, the at least one carboxylic acid can be chosen from saturated or unsaturated, substituted or unsubstituted dicarboxylic acids, salts thereof, and mixtures thereof. By way of non-limiting example, the at least one carboxylic acid can be chosen from among dicarboxylic acids of the following formula:
wherein: -R is a C1-C100 cyclic or acyclic hydrocarbon moiety, saturated or unsaturated, linear or branched, comprising from 0 to 30 double and/or triple bonds and/or from 0 to 10 rings, and optionally interrupted by 1 to 30 heteroatoms chosen from O, N and S, and optionally substituted with 1 to 30 substituents chosen from a hydrogen atom, a hydroxyl moiety (-OH), an amino moiety (-NH2), an alkyl (C1-C30)amino moiety , a poly(C1-C30)alkylamino moiety, a hydroxy(C1-C30)alkylamino moiety, a polyhydroxy(C1-C30)alkylamino moiety, a C6-C30 aryl moiety, and in some embodiments -R may be omitted; and -X and X' independently denote a hydrogen atom, an ammonium ion, an alkali metal ion such as Li, Na, K, or an alkaline earth metal such as Be, Mg, Ca or an ion derived from an organic amine as an alkylamine.
[00159] It is understood that the term cyclic hydrocarbon portion for the purposes of the present application is understood to mean a hydrocarbon portion consisting of one or more rings or comprising one or more rings that are pendant or on the main chain, it being possible for the rings to be saturated or unsaturated and are substituted with one or more C1-C30 alkyl or alkenyl or hydroxyl or amino moieties.
[00160] By way of non-limiting example only, carboxylic acids useful in the conditioning composition may include oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, maleic acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and also combinations thereof. In at least one embodiment, the conditioning composition comprises at least one carboxylic acid other than maleic acid.
[00161] It should be noted, however, that the carboxylic acid chosen for the conditioning composition may be the same or different from the at least one carboxylic acid chosen for the treatment composition.
[00162] It should be noted, however, that the carboxylic acid chosen for the conditioning composition may be the same or different from the at least one carboxylic acid chosen for the treatment composition. In at least one embodiment, the conditioning composition comprises maleic acid and/or citric acid, and optionally at least one additional carboxylic acid. In further embodiments, the conditioning composition comprises at least one carboxylic acid other than maleic acid and/or citric acid. In additional embodiments, the conditioning composition is free or substantially free of maleic acid.
The conditioning composition may, in various embodiments, be in the form of an emulsion, and may optionally comprise additional components, for example, surfactants, solvents, and/or conditioning agents, and also other additives.
[00164] By way of non-limiting example, the solvent may be chosen from cosmetically acceptable solvents chosen from water, at least one cosmetically acceptable organic solvent, and mixtures thereof.
[00165] Organic solvents can be volatile or non-volatile compounds. As examples of organic solvents, non-limiting mentions may be made to monoalcohols and polyols such as ethanol, isopropyl alcohol, propyl alcohol, benzyl alcohol, and phenylethanol, or glycols or glycol ethers such as, for example, ethylenic glycol monomethyl, monoethyl and monobutyl ethers , of propylene glycol or ethers thereof such as, for example, propylene glycol, butyl glycol, hexylene glycol, dipropylene glycol monomethyl ether, and also diethylene glycol alkyl ethers, for example monomethyl ether or glycol monobutyl ether diethylenic. Other suitable examples of organic solvents are ethylenic glycol, propylene glycol, butylenic glycol, hexylene glycol, propanediol, and glycerin.
[00166] The cosmetically acceptable solvent may comprise an amount in the range of up to about 98%, such as up to about 95%, such as up to about 90%, up to about 85%, up to about 80%, up to about 75 %, up to about 70%, up to about 65%, up to about 60%, up to about 55%, or up to about 50%, by weight, based on the weight of the conditioning composition. For example, the cosmetically acceptable solvent can range from about 80% to about 98% by weight, such as from about 85% to about 95% by weight, based on the weight of the conditioning composition.
Conditioning agents that may be included in the conditioning composition include, but are not limited to, cationic, nonionic, and amphoteric conditioning agents. For example, cationic conditioning agents can be chosen from polyquaternium-10 (also called quaternized polyhydroxyethylcellulose), cetrimonium chloride (also called cetyltrimethylammonium chloride, CTAC), behetrimonium chloride (also known as docosyltrimethylammonium chloride), methosulfate of behetrimonium, steartrimonium chloride, stearalkonium chloride, dicetyldimonium chloride, hydroxypropyltrimonium chloride, cocotrimonium methosulfate, olealkonium chloride, steartrimonium chloride, babassuamidopropalkonium chloride, brassicamidopropyldimethylamine chloride, Quaternium-91, Salcare/PQ-37, Quaternium -22, Quaternium-87, Polyquaternium-4, Polyquaternium-6, Polyquaternium-11, Polyquaternium-44, Polyquaternium-67, amodimethicone, laurylbetaine, Polyacrylate-1 Cross-Polymer, Steardimonium-hydroxypropyl-hydrolyzed wheat protein, behenamidopropyl chloride -PG-dimonium, lauryldimonium-hydroxypropyl-hydrolyzed soy protein, aminopropyldim ticone, Quaternium-8, and dilinoleamidopropyldimethylaminedimethicone-PEG-7 phosphate.
[00168] Amphoteric conditioning agents can be chosen from polyquaternium-22, polyquaternium-39, polyquaternium-47, polyquaternium-53, arginine, asparagines, aspartic acid, glycine, glutamic acid, lysine, methionine, phenylalanine, serine, threonine, tyrosine tryptophan, valine, gelatin, Quaternium-27, oleamidopropylbetaine, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodiacetate, sodium cocoamphopropionate, sodium cocoamphoacetate, coconidopropylamidobetaine, delta-lactone of meadowforamidopropylamidobetin, cocothenidopropylamidobetin, limidopropylamidobetin, limidopropylamidobetin , hydroxyproline, acetylhydroxyproline, isoleucine, lauroyllysine, lauroylsarcosine, polylysine, proline, rice amino acids, silk amino acids, and wheat amino acids.
[00169] Additional auxiliary components that may be present in the conditioning composition include, but are not limited to, coloring agents, emulsifiers, thickening agents and rheology modifying agents, cationic polymers, wetting and moisturizing agents, chelating agents such as glycine, different emulsifying agents from those belonging to the above described fatty substances, fillers, structuring agents, propellants, anionic surfactants, cationic surfactants, amphoteric surfactants, brightening agents, conditioning agents, brightening agents, and reinforcing agents.
[00170] If present, the at least one auxiliary component may be present in an amount of up to about 25%, such as up to about 20%, up to about 15%, up to about 10% by weight, such as about 0 .1% to about 10% by weight, from about 0.5% to about 5%, or from about 1 to about 3% by weight, based on the total weight of the conditioning composition.
The pH of the conditioning composition can range from about 1 to about 7, such as from about 2 to about 5, or from about 3 to about 4.
According to various embodiments, the conditioning composition can include at least one monoamine and a combination of carboxylic acids. By way of non-limiting example, the conditioning composition can include at least one monoamine and a combination of two carboxylic acids, such as malonic acid and citric acid, malonic acid and oxalic acid, malonic acid and maleic acid, malonic acid and malic acid, acid citric acid and oxalic acid, citric acid and maleic acid, citric acid and malic acid, oxalic acid and maleic acid, oxalic acid and malic acid, maleic acid and malic acid, and so on. In additional embodiments, the conditioning composition can include at least one monoamine and combinations of three or more carboxylic acids.
In some embodiments, the conditioning composition can include at least one monoamine and one or more saturated carboxylic acids and can be free or substantially free of unsaturated carboxylic acids. In some embodiments, the conditioning composition can include at least one monoamine and one or more unsaturated carboxylic acids, and can be free or substantially free of saturated carboxylic acids. In still other embodiments, the conditioning composition can include at least one monoamine and both saturated carboxylic acids (eg, oxalic acid, malonic acid, glutaric acid, succinic acid, adipic acid, glycolic acid, citric acid, tartaric acid, malic acid, acid sebacic acid, glyoxylic acid monohydrate) or unsaturated carboxylic acids (maleic acid, fumaric acid, benzoic acid, citraconic acid).
[00174] Treatment and/or conditioning compositions, according to the description, may be in various forms, such as in the form of liquids, creams, liquid-gels, liquid-creams, gels, lotions, or pastes.
In certain exemplary embodiments, the conditioning composition can include from about 0.1% by weight to about 5% by weight of monoamine, such as from about 0.5% by weight to about 3% by weight, or from about 0.5% by weight to about 2% by weight of the monoamine, such as from about 0.5% by weight to about 1% by weight, based on the weight of the conditioning composition. In certain exemplary embodiments, the conditioning composition may include from about 0.1% by weight to about 5% by weight of carboxylic acids, as in accordance with 0.5% by weight to about 4% by weight, or of about 0.75% by weight to about 3% by weight, such as from about 1% by weight to about 2% by weight of carboxylic acids, based on the weight of the conditioning composition.
By way of non-limiting example only, the conditioning composition includes from about 0.5% by weight to about 2% by weight of monoamine and from about 0.75% by weight to about 3% by weight of one or more carboxylic acids, such as from about 0.5% by weight to about 1% by weight 3-MPA and from about 1% by weight to about 2% by weight of one or more carboxylic acids, based on the weight of the conditioning composition. By way of non-limiting example, the conditioning composition may include from about 5% by weight to about 6% by weight monoamine and from about 1% by weight to about 2% by weight maleic acid, based on the weight of the conditioning composition.
[00177] According to certain embodiments, the total combined amount of monoamine and carboxylic acid present in the conditioning composition can be in the range of up to about 20%, such as from about 0.5% to about 15%, of about 1% to about 15%, from about 1% to about 10%, from about 2% to about 8%, from about 2% to about 5%, or about 3% to about 5 % by weight, based on the weight of the conditioning composition.
Without intending to limit the description, it may, in various embodiments, be advantageous to choose certain amounts of the monoamine, at least one carboxylic acid, solvent, and/or optionally any additional component in the conditioning composition, or component ratios in relationship with one another, for the purpose of providing or improving the synergistic results of their combinations.
[00179] Treatment and/or conditioning compositions, according to the description, can be in various forms, such as in the form of liquids, creams, liquid-gels, liquid-creams, gels, lotions, or pastes. METHODS
[00180] As described herein, treatment and/or conditioning compositions, and/or systems comprising the treatment and conditioning compositions, can be used to treat hair, for example before, during, and/or after a process to chemically change the color or shape of hair, and/or as a stand-alone treatment for damaged hair. For example, a color or shape altering composition can comprise a treatment composition, or the treatment composition can comprise a color or shape altering composition or agent or composition. It should be understood that when "a color altering composition comprises the treatment composition", "a shape altering composition comprises the treatment composition", "the treatment composition comprises a color changing composition", "the treatment composition comprises a format altering composition”, or the like, the two compositions or their components are mixed together, but without any limitation, for example on which composition is added to which composition or the order of mixing.
[00181] In further embodiments, the treatment composition may be applied to the hair first, and optionally shampooed and/or rinsed off, after which a color or shape altering composition, or a composition that is not a color or shape altering composition is applied to the hair. In various embodiments, the conditioning composition can be applied to the hair after the treatment composition and/or the color or shape altering composition is applied to the hair, and optionally shampooed and/or rinsed off.
[00182] As used herein, treatment compositions can be applied to hair "before" chemical hair treatment, such as before structuring (shaping), coloring, or lightening the hair, with or without shampooing. or removal by intermediate rinse, such as less than one minute before, up to about 5 minutes before, up to about 10 minutes before, up to about 20 minutes before, up to about 30 minutes before, up to about 1 hour before, up to about 2 hours before, up to about 6 hours before, up to about 12 hours before, up to about 24 hours before, up to about 48 hours before, up to about 72 hours before, or up to about 1 week before.
[00183] As used herein, the treatment compositions can be applied to hair "after" the chemical treatment of the hair, such as after structuring (shaping), coloring, or lightening the hair, with or without shampooing. or removal by intermediate rinse, for example, less than one minute after, until about 5 minutes after, up to about 10 minutes after, up to about 20 minutes after, up to about 30 minutes after, up to about 1 hour after, up to about 2 hours after, to about 6 hours after, to about 12 hours after, to about 24 hours after, to about 48 hours after, to about 72 hours after, or up to about 1 week after.
[00184] As used herein, the treatment compositions can be applied to hair "during" the chemical treatment of the hair, for example simultaneously with or at approximately the same time as the chemical treatment such as structuring (shaping), coloring or lightening the hair. hair, for example, by combining or mixing the treatment composition with the chemical treatment composition prior to applying the mixture to the hair. By way of example, the treatment compositions may be mixed with a color or shape change composition in an amount in the range of about 30% by weight, relative to the weight of the color change composition, such as up to about 25% , up to about 20%, or up to about 15% by weight, relative to the weight of the color altering composition. For example, the treatment composition can be mixed with a color or shape change composition in an amount ranging from about 1% to about 20%, from about 2% to about 15%, from about 3 % to about 13%, or from about 4% to about 10% by weight, relative to the weight of the color altering composition. In still other exemplary embodiments, the treatment composition and the color or shape altering composition can be applied to the hair at substantially the same time, but from separate applicators without mixing prior to application to the hair, either with or without shampooing. or removal by intermediate rinse.
By way of non-limiting example, a method of treating or changing the shape or color of hair may comprise applying the treatment composition to the hair as a composition for pre-relaxation, permanent pre-curl, pre-smoothing, pre-staining, pre-glazing, or pre-lightening, which can optionally be left on the hair or washed off before applying the color or shape change composition. In another exemplary embodiment, a method may comprise adding the treatment composition to a color or shape altering composition, optionally immediately prior to use, and applying the mixture to the hair. In yet another exemplary embodiment, a method may comprise adding a color or shape altering agent, for example an oxidizing agent or dye, to the treatment composition, optionally immediately prior to use, and applying the treatment composition to the hair. In yet another exemplary embodiment, a method may comprise mixing a structuring agent (shape changer) or coloring or bleaching composition and developing composition immediately before use, wherein the treatment composition may be pre-formulated into the structuring or coloring composition or bleaching, or revealing composition. In yet another exemplary embodiment, a method may comprise applying the conditioning composition to the hair as an after-treatment composition after the hair has been treated and after optionally rinsing or washing the hair.
[00186] The term "mixing" and all variations of this term, as used herein, refers to contacting or combining or reconstituting or dissolving or dispersing or blending with or agitating the composition for treatment with the color or color altering composition. Format. It may also mean introducing the composition for treatment into the color or shape altering composition. It can also mean positioning the composition for treatment within the same vessel or container as the color altering composition.
[00187] As another example, a treatment composition according to the description can be applied to hair after the reducing step of a hair treatment process, for example a relaxer, straightener, or permanent wave. After the optional leave-in (no rinse) (processing) time, for example, of about 5-10 minutes, such as about 10-15 minutes, the hair can optionally be dried with an absorbent material or rinsed, and then the conditioning composition is applied to the hair, and optionally shampooed or rinsed off. Without wishing to be bound by theory, it is believed that the reducing step of the process swells the hair cuticle, making it able to accept the active component(s) of the treatment composition, and the conditioning composition, then , deflates the hair cuticle, sealing the active component(s) in it.
[00188] In still other exemplary embodiments, the treatment composition, the conditioning composition, or systems comprising the treatment composition and the conditioning composition, may be applied to the hair not in conjunction with the color changer or shape changer process or the color-altering or shape-altering composition. Such treatment compositions, conditioning compositions, and/or systems comprising the treatment composition and the conditioning composition may be useful to provide cosmetic advantages such as shine, conditioning, fiber strength, and/or healthy appearance to hair, separate and apart. avoid or minimize hair damage caused by chemical processes such as coloring, discoloring, structuring, relaxing, etc., of the hair.
[00189] By way of non-limiting example only, a treatment composition, according to the description, can be mixed with a composition that does not contain an agent to change the color or shape of the hair, can be applied directly to the hair, for example simultaneously with a composition that does not contain an agent to change the color or shape of the hair, or it can be mixed with water and applied to the hair, and optionally the hair can be shampooed and/or rinsed, after which a The conditioning composition, according to the description, can be applied to the hair, and optionally subjected to shampooing and/or rinsing off.
[00190] In another exemplary modality, the methods refer to processes for hair treatment in which only a portion of the hair is subjected to a chemical process such as a color or shape change process. By way of example, when hair is lightened, only certain portions of the hair on a consumer's head are treated with a bleaching or bleaching agent. However, different portions of hair can be treated (e.g., lightened) during subsequent color or shape change processes, thereby causing, over time, more damage to certain portions of the hair. Thus, it may be desirable in such embodiments to treat the entire head of hair with a treatment composition as described. As such, in various embodiments, a treatment composition, in accordance with the description, can be applied to certain portions of the hair in conjunction with a bleaching or bleaching process or hair dyeing or structuring (eg, mixed with a bleaching or lightening composition. or hair dyeing or structuring), while a treatment composition, according to the description, can be applied to other portions of the hair that have not been subjected to the chemical process, for example in a composition not containing a coloring or structuring agent. hair. Although some overlapping of the treated portions of hair may occur, various modalities contemplate that the treated hair will essentially consist of different portions of hair.
[00191] Accordingly, methods for changing the color or shape of hair are within the scope of the description wherein a first treatment composition comprising monoamine; at least one carboxylic acid chosen from oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, maleic acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; at least one solvent; and at least one agent to change the shape or color of the hair is applied to certain portions of the hair; and a second treatment composition comprising monoamine; at least one carboxylic acid chosen from oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, maleic acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one solvent; wherein the second treatment composition does not contain an agent to change the shape or color of the hair, it is applied to different portions of the hair. The second treatment composition can, for example, be applied directly to the hair, or it can be mixed with water or with a composition such as a clear glaze. Optionally, a conditioning composition, in accordance with the description, can also be applied to the hair, e.g., to a portion of the hair, or to the entire treated hair. In various embodiments, it may be possible for the at least one carboxylic acid in the first and second treatment compositions and/or conditioning composition to be the same or different, and the at least one carboxylic acid for each should be understood to be chosen independently.
[00192] In various exemplary methods or processes, the treatment composition or mixture comprising the treatment composition can be applied to the hair, and after an optional leave-on (no rinse) time on the hair fibers, for example, in the range of from about 1 to about 60 minutes, such as from about 5 to about 50 minutes, or as from about 5 to about 30 minutes, or as from about 10 to about 20 minutes, or as of about 20 minutes, the hair fibers can be rinsed, optionally shampooed and rinsed again, the conditioning composition can be applied to the hair fibers, and after an optional second rest time, the hair fibers can optionally be washed with a hair conditioning composition, rinsed again, and then dried. The conditioning composition can be left on the hair for a rest or leave-in (no rinse) period in the range of up to about 60 minutes, such as from about 1 to about 30 minutes, or from about 5 to about 15 minutes. The shampoo and hair conditioning composition can be any conventional shampoo and/or hair conditioner products.
[00193] The temperature during hair treatment methods can be, for example, between room temperature and 80°C, such as between room temperature and 60°C, or between room temperature and 40°C.
[00194] It has been found that the application of the treatment composition, the conditioning composition, or a system comprising the treatment composition and the conditioning composition onto the fibers, together with a process for changing the color and/or shape of the hair, results in "lifting" or satisfactory lightening of the color of the fibers, or alteration of the shape of the hair fibers, while providing strength and/or protection to the hair fiber so as to minimize damage to the hair fiber in at least some modalities . Furthermore, when the composition modalities comprise a coloring compound selected from oxidative dye precursors, direct dyes, pigments or mixtures thereof, the fibers are also colored satisfactorily with respect to the degree of dye deposition and coloring with desirable nuance formation, while that provide strength and/or protection to the hair fiber so as to avoid or minimize damage to the hair fiber in at least some modalities.
[00195] It is to be understood that any degree of protection and/or strength and/or damage minimization may be granted to the hair fiber, without limitation. Furthermore, it is intended that modalities which do not impart fiber strength and/or protection and/or damage minimization to the hair fiber are also within the scope of the description. KITS
[00196] Other modalities of the description refer to kits for treatment and/or changing the color and/or shape of hair. An exemplary embodiment of a kit for treating and/or altering hair color comprises: A. a first compartment containing a treatment composition comprising: i. at least one monoamine; ii. at least one carboxylic acid; and iii. optionally at least one solvent; and B. a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid; and C. optionally, one or more additional compartments comprising at least one hair coloring agent or hair coloring composition.
[00197] An exemplary embodiment of a kit for treating and/or altering the shape of hair comprises: A. a first compartment containing a composition for treatment comprising: i. at least one monoamine; ii. at least one carboxylic acid; and iii. optionally at least one solvent; and B. a second compartment containing a conditioning composition comprising at least one monoamine and at least one carboxylic acid; and C. optionally, one or more additional compartments comprising at least one agent or composition for structuring (shaping) hair,
[00198] Other exemplary embodiments of a kit for treating and/or altering hair color comprise: A. a first compartment containing a composition for treatment comprising: i. at least one monoamine; ii. at least one carboxylic acid; and iii. optionally at least one solvent; and B. a second compartment containing a conditioning composition comprising monoamine and at least one carboxylic acid; and C. optionally, one or more additional compartments comprising at least one hair coloring agent or hair coloring composition, the first compartment and/or second compartment comprising at least one acid chosen from maleic acid, citric acid, or mixtures of the same.
[00199] An exemplary embodiment of a kit for treating and/or altering the shape of hair comprises: A. a first compartment containing a composition for treatment comprising: i. at least one monoamine; ii. at least one carboxylic acid; and iii. optionally at least one solvent; and B. a second compartment containing a conditioning composition comprising monoamine and at least one carboxylic acid; and C. optionally, one or more additional compartments comprising at least one agent or composition for structuring (shaping) hair,
[00200] Other exemplary embodiments of a kit for treating and/or altering the shape of hair comprise: A. a first compartment containing a composition for treatment comprising: i. at least one monoamine; ii. at least one carboxylic acid; and iii. optionally at least one solvent; and B. a second compartment containing a conditioning composition comprising monoamine and at least one carboxylic acid; and C. optionally, one or more additional compartments comprising at least one agent or composition for structuring (shaping) hair, wherein the first compartment and/or the second compartment and/or one or more additional compartments are exempt or substantially free of maleic acid.
[00201] Other exemplary embodiments of a kit for treating and/or altering the shape of hair comprise: A. a first compartment containing a composition for treatment comprising: i. at least one monoamine; ii. at least one carboxylic acid; and iii. optionally at least one solvent; and B. a second compartment containing a conditioning composition comprising monoamine and at least one carboxylic acid; and C. optionally, one or more additional compartments comprising at least one agent or composition for structuring (shaping) hair, wherein the first compartment and/or second compartment and/or one or more additional compartments comprise at least one acid chosen from maleic acid, citric acid, or mixtures thereof.
[00202] According to various modalities, the at least one carboxylic acid present in the hair treatment composition and/or hair conditioning composition of any of the aforementioned kits can be independently chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof. In some embodiments, the at least one carboxylic acid in the treatment composition and the conditioning composition in the first compartment and the second compartment of the kit are the same. In further embodiments, the at least one carboxylic acid in the treatment composition and the conditioning composition in the first compartment and the second compartment of the kit are different.
[00203] In some embodiments, the at least one carboxylic acid present in the hair treatment composition and/or hair conditioning composition in the first compartment and second compartment of the kit are independently chosen from malonic acid, maleic acid, citric acid, and combinations thereof. In additional embodiments, the at least one carboxylic acid present in the hair care composition and/or hair conditioning composition in the first compartment and second compartment of the kit are independently chosen from citric acid, malonic acid, oxalic acid, malic acid, glutaric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, sebacic acid, glyoxylic acid monohydrate, and combinations thereof. In still other embodiments, the at least one carboxylic acid is chosen from maleic acid, citraconic acid, fumaric acid, benzoic acid, and combinations thereof. In still other modalities, the carboxylic acid present in the composition for treatment in the first compartment, the carboxylic acid present in the conditioning composition in the second compartment, or both, can be independently chosen from combinations of two carboxylic acids, chosen from malonic acid and citric acid ; malonic acid and oxalic acid; malonic acid and maleic acid; malonic acid and malic acid; citric acid and oxalic acid; citric acid and maleic acid; citric acid and malic acid; oxalic acid and maleic acid; oxalic acid and malic acid; maleic acid and malic acid. In still other embodiments, the carboxylic acid present in the treatment composition, the carboxylic acid present in the conditioning composition, or both, can be independently chosen from combinations of three or more carboxylic acids.
[00204] In an exemplary and non-limiting modality, the at least one carboxylic acid present in the composition for treatment in any of the aforementioned kits is chosen from citric acid or maleic acid. In other exemplary and non-limiting embodiments of the aforementioned kits, the at least one carboxylic acid present in the treatment composition and the at least one carboxylic acid present in the conditioning composition are chosen from citric acid or maleic acid.
[00205] It is to be understood that, as used herein, the terms "the", "the", "a" or "an" mean "at least one", and should not be limited to "only one". a)” unless explicitly stated otherwise. Thus, for example, reference to "a portion" includes examples having two or more such portions unless the context clearly indicates otherwise.
[00206] Unless expressly stated otherwise, it is not intended in any of the methods presented herein to be construed as requiring that its steps be performed in a specific order. Consequently, if a method claim does not actually cite an order to be followed by its steps or it is not specifically stated otherwise in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any specific order is inferred.
[00207] Although various features, elements or steps of specific modalities may be described using the transitional phrase "comprising", it is to be understood that alternative modalities, including those that may be described using the transitional phrases "consisting of" or “consisting essentially of”, are implied. Thus, for example, implicit alternative modalities relating to a method comprising A+B+C include modalities in which a method consists of A+B+C and modalities in which a method consists essentially of A+B+C. As described, the phrase "at least one of A, B, and C" is intended to include "at least one A or at least one B or at least one C", and is also intended to include "at least one A and at least one B and at least one C”.
[00208] All ranges and quantities presented herein are intended to include subranges and quantities using any point described as an endpoint. Thus, a range of "1% to 10%, such as 2% to 8%, such as 3% to 5%", is intended to include the ranges from "1% to 8%, from "1% to 5 %”, from “2% to 10%”, and so on. All numbers, quantities, ranges, etc., are intended to be modified by the term “about”, whether expressly or not expressly stated. Similarly, a given range of "about 1% to 10%" is intended to have the term "about" modifying both the 1% endpoint and the 10% endpoint.
[00209] Notwithstanding, the numerical ranges and parameters presenting the broad scope of the description are approximations, unless otherwise indicated the numerical values presented in the specific examples are reported as accurately as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective test measurements. The following example serves to illustrate the embodiments of the present description without, however, being of a limiting nature.
[00210] It is to be understood that the term "monoamine" is intended to mean "one or more monoamines" throughout the specification and claims, regardless of whether or not it is so specified, unless specifically indicated to the contrary.
[00211] It will be evident to those skilled in the art that various modifications and variations can be made to the system, composition and release methods of the invention without departing from the spirit and scope of the invention. Accordingly, it is intended that the present invention cover the modifications and variations of this invention provided they are within the scope of the appended claims and their equivalents. EXAMPLES
[00212] The amounts of ingredients in the compositions/formulations described below are expressed in % by weight, based on the total weight of the composition, unless otherwise indicated. Examples 1-1 to 1-13 Compositions
The following exemplary treatment compositions were prepared comprising at least one monoamine, at least one carboxylic acid, wherein the carboxylic acid is chosen from maleic acid, and at least one solvent. In Table 1, the amounts shown are % by weight of the treatment composition, and the pH of each of the treatment compositions is approximately 3.0. Table 1:


The exemplary treatment compositions of Table 1 can be applied to the hair before or after a color changing composition, or can be mixed with a color changing composition for simultaneous application with the color changing composition.
The following conditioning compositions were prepared by mixing formulations 2b-1 to 2b-8 of Table 2b into the composition of Table 2a. In Tables 2a-2b, the amounts shown are % by weight of the conditioning composition. Table 2a:
Table 2b:

The conditioning compositions prepared by mixing the formulations in Tables 2a and 2b can be applied to the hair after the hair is treated with a treatment composition and/or a color changing composition and/or a shape changing composition as herein. described. Methods
[00217] The following are examples of methods or processes for treating hair in vitro and in vivo. Example-In vitro Discoloration Process
[00218] A conventional bleach (30g) and a conventional developer (30-60g) can be mixed with a treatment composition (8g), the mixture can be applied to the hair, and left on the hair for 50 minutes or more to achieve a lift equal to that of hair treated with standard bleach for 50 min. Processing can be carried out at room temperature. The hair can be rinsed, after which a conditioning composition (0.4g/g of hair) can be applied to the hair and allowed to rest for 10 minutes at room temperature, and then the hair can be rinsed. Hair can be shampooed and rinsed, and conditioner can be applied to hair and hair can be rinsed. Example-In vivo Discoloration Process
[00219] A conventional bleach (30g) and a conventional developer (30-60g) can be mixed with a treatment composition (8g), the mixture can be applied to the hair, and left on the hair for up to 50 minutes or until the desired lift at room temperature is achieved. The hair can be rinsed, after which a conditioning composition (15g-30g) can be applied to the hair and allowed to rest for 10 minutes at room temperature, and then the hair can be rinsed. Hair can be shampooed and rinsed, and conditioner can be applied to hair and hair can be rinsed. Example-In vivo Shine Bath Process
[00220] A conventional shine bath (Shades EQ, 60g) and a conventional processing solution (60g) can be mixed with a treatment composition (4g), the mixture can be applied to the hair, and left on the hair for about 20 minutes at room temperature. The hair can be rinsed, after which a conditioning composition (15-30g) can be applied to the hair and allowed to stand for 10 minutes at room temperature, and then the hair can be rinsed. Hair can be shampooed and rinsed, and conditioner can be applied to hair and hair can be rinsed. Example-In vivo Bleaching and Shine Bath Process
[00221] A conventional bleach (30g) and a conventional developer (30-60g) can be mixed with a treatment composition (8g), the mixture can be applied to the hair, and left on the hair for up to 50 minutes or until the desired lift is achieved. Hair can be rinsed and shampooed. A conventional shine bath (Shades EQ, 60g) and a conventional processing solution (60g) can be mixed with a treatment composition (4g), the mixture can be applied to the hair, and left on the hair for about 20 minutes at room temperature. The hair can be rinsed, after which a conditioning composition (15-30g) can be applied to the hair and allowed to stand for 10 minutes at room temperature, and then the hair can be rinsed. Hair can be shampooed and rinsed, and conditioner can be applied to hair and hair can be rinsed. Examples of compositions for in vitro treatment
The following exemplary treatment compositions as set forth in Table 3 were prepared and adjusted to pH 3 except where otherwise indicated. In Table 3, the amounts shown are % by weight of the treatment composition, with the remainder of each composition being water. The hair treatment selected was a standard conventional bleach including a bleach composition (30g) and a developer (30-60g) was mixed with each treatment composition (8g). The mixture was applied to repeated hair samples under the aforementioned conditions. Hair samples were then washed and evaluated. All examples were conducted to achieve the same level of “lift” (level of whitening). The time has been adjusted accordingly. This allows for a direct comparison of the level of damage done to the hair.
[00223] The evaluations of the hair samples treated with the exemplary compositions were compared with the evaluations of the hair samples treated with a standard bleaching composition, with just acid or amine, or with acid or amine with pH adjusted to about 3. Results Cysteic Acid Data
[00224] Since the amount of cysteic acid is an indication of the level of damaged hair, a lower measured concentration indicates that a specific composition provided a protective benefit to the hair fiber. Therefore, the measured concentration of cysteic acid is a marker with respect to the assessment of fiber integrity. A 10% improvement (% relative change) is typically considered to be statistically significant, such as an increase in fiber integrity.
Portions of hair samples (sample collection) were cut and weighed to approximately 20 mg, hydrolyzed under strong acidic conditions for 16 hours at 110°C. After being hydrolyzed, the samples were pH adjusted to approximately 1.7 with a lithium hydroxide solution and analyzed on a Hitachi Model 8900 amino acid analyzer. Amino acid standards obtained from Sigma Aldrich (Ref AAS18) were used to calibrate the instrument and to calculate the amino acid concentration for each of the treatment conditions. The compositions shown in Table 3, below, show the cysteic acid measurements of the compositions in Table 3, which were compared with samples treated with only a standard bleach (bleach and developer composition) and with compositions not containing 3-MPA and fur minus one carboxylic acid. “Miniature” Tensile Tester Data
Hair samples with treatment compositions containing standard bleaching compositions containing 3-MPA were evaluated for tensile strength using a fiber tensile tester instrument available from Dia-Stron, known as MTT ("Miniature Tensile Tester" ”). For each sample, 50 fibers were tested. From the test, the Young's Modulus (elasticity, MPa) and the breaking strength (force per unit area required to break the fiber, MPa) were determined. The test results are shown below in Table 4. Raw Data Table 3: Cysteic Acid Data

Table 4: MTT data

[00227] Based on the MTT results in Table 4, it is evident that a bleach blend with the combination of 3-MPA and a carboxylic acid provides a great improvement in elastic modulus and tensile strength compared to bleach alone , and also with the other examples in the comparison, for an equivalent “lift” (level of lightening). The combination of 3-MPA and a carboxylic acid therefore provides improved break strength to hair treated with a blend comprising the combination. Resistance and tactile substance
[00228] Hair samples treated with the exemplifying treatment compositions were tested for tactile substance versus hair samples treated with 3-MPA alone, 3-MPA pH adjusted with hydrochloric acid to pH about 3, carboxylic acid alone, and pH-adjusted carboxylic acid with sodium hydroxide to a pH of about 3.
[00229] The evaluation of strength (hair that is easy to untangle and comb, having an above average bending strength) and tactile substance (smooth surface feel, when pulled maintains elasticity) was performed visually and by sensation by expert evaluators in wet hair sample, and each sample was rated for each property. The results are shown in Table 5 and Figs. 1-5, where the increase (positive change) and decrease (negative change) are relative to the standard bleach, considered as the baseline (0). Table 5: Sensory Comparisons


[00230] As shown in Table 5 and Figs. 1-5, the best combinations of tactile substance and strength resulted from compositions including 3-MPA and at least one carboxylic acid. Highlighted comparisons
[00231] For Comparisons 1-2, below, the cysteic acid and MTT data are reproduced from the tables above, but not the sensory data. Note that the sensory conclusions are based on the data shown in the tables from the previous raw data section. Comparison 1: Citric Acid ± 3-MPA Table 6: Comparison 3-MPA and Citric Acid

[00232] As shown in Table 6, the combination of 3-MPA and citric acid reduced the cysteic acid content compared to the bleach alone and all other examples in the comparison. Based on the MTT results, this combination of ingredients also showed an increase in elastic modulus and tensile strength compared to bleach alone. Sensory data showed that the combination had vastly higher strength without harming the tactile substance, when compared to the bleach alone and all the other examples of bleach combined with additives in the dataset. Comparison 2: Maleic Acid ± 3-MPA Table 7: Comparison 3-MPA and Maleic Acid

As shown in Table 7, the combination of 3-MPA and maleic acid improved the cysteic acid content more than the amine alone, the pH adjusted maleic acid, or the bleach alone. Based on the MTT results, this combination of ingredients also showed a large increase in elastic modulus and tensile strength compared to bleach alone and all the examples in the comparison. Sensory data showed that the combination had vastly higher strength without harming the tactile substance, when compared to the bleach alone and all the other examples of bleach combined with additives in the dataset.

权利要求:
Claims (23)
[0001]
1. Composition for hair treatment, characterized in that it comprises: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine , and combinations thereof, or combinations comprising at least two teeth: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2-aminoethoxy) )ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; wherein at least one carboxylic acid is present in an amount of up to about 30% by weight, based on the weight of the hair treatment composition; and at least one solvent, at least one additive or combinations thereof.
[0002]
2. Composition for hair treatment according to claim 1, characterized in that the at least one carboxylic acid is chosen from citric acid, malonic acid, oxalic acid, malic acid, glutaric acid, glycolic acid, succinic acid, adipic acid , tartaric acid, sebacic acid, glyoxylic acid monohydrate, and combinations thereof, or wherein the at least one carboxylic acid is chosen from maleic acid, citraconic acid, fumaric acid, benzoic acid, and combinations thereof, preferably wherein the at least one carboxylic acid is chosen from maleic acid, citric acid and combinations thereof.
[0003]
A hair care composition according to claim 1 or 2, characterized in that the monoethanolamine is present in an amount in the range of up to about 10% by weight, based on the weight of the hair care composition.
[0004]
4. Hair treatment composition according to any one of claims 1 to 3, characterized in that the composition is a hair treatment composition or a hair conditioning composition.
[0005]
5. Composition for hair treatment according to any one of claims 1 to 4, characterized by the fact that the solvent is chosen among water, cosmetically acceptable organic solvents, and combinations thereof.
[0006]
6. Composition for hair treatment according to any one of claims 1 to 4, characterized by the fact that the additive is chosen from surfactants, solvents, and/or conditioning agents.
[0007]
7. A hair care system, characterized in that it comprises: (a) the hair care composition as defined in claim 1; and (b) a hair conditioning composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)propylamine, and combinations thereof, or combinations comprising at least two of: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2-aminoethoxy)ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one additive.
[0008]
8. Hair treatment system according to claim 7, characterized in that the at least one carboxylic acid present in the hair treatment composition and/or hair conditioning composition is independently chosen from citric acid, malonic acid, acid oxalic, malic acid, glutaric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, sebacic acid, glyoxylic acid monohydrate, and combinations thereof, or wherein the at least one carboxylic acid present in the hair care composition and/or in the hair conditioning composition are independently chosen from maleic acid, citraconic acid, fumaric acid, benzoic acid, and combinations thereof, preferably wherein the at least one carboxylic acid present in the hair care composition and/or composition Hair conditioners are independently chosen from maleic acid, citric acid and combinations thereof.
[0009]
9. Hair treatment system according to claim 7 or 8, characterized in that it further comprises a composition or an agent for coloring or structuring (shaping) the hair, preferably wherein the composition for coloring or structuring (alteration of the shape) of the hair comprises the hair treatment composition, more preferably: a) wherein the coloring agent is chosen from bleaching agents, coloring compounds, or combinations thereof, preferably wherein the at least one coloring compound is chosen from oxidative dyes, direct dyes, pigments, and mixtures thereof, and/or the hair structuring agent is chosen from agents for straightening, relaxing, or permanent hair curling, and b) wherein the at least one bleaching agent is chosen from peroxides, persulfates, perborates, percarbonates, peracids, bromates, their salts, and mixtures thereof.
[0010]
10. A hair care system, characterized in that it comprises: (a) the hair care composition as defined in claim 1, wherein the monoamine is: 3-methoxypropylamine; and the at least one carboxylic acid is chosen from citric acid and maleic acid; and (b) a hair conditioning composition comprising: 3-methoxypropylamine; at least one carboxylic acid chosen from citric acid and maleic acid, preferably maleic acid; and at least one additive.
[0011]
11. Hair treatment system according to claim 10, characterized in that it additionally comprises a composition or an agent for coloring or structuring (shaping) the hair.
[0012]
12. Hair treatment method, said method characterized in that it comprises: (a) applying to the hair the hair treatment composition as defined in claim 1; and at least one solvent; and (b) optionally shampooing and/or rinsing the hair; (c) applying to the hair a hair conditioning composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)propylamine, and combinations thereof, or combinations comprising at least two of: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2-aminoethoxy) ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one additive; and (d) optionally shampooing and/or rinsing the hair.
[0013]
13. Method according to claim 12, characterized in that the at least one carboxylic acid present in the hair treatment composition and/or hair conditioning composition is independently chosen from maleic acid, citric acid, and combinations thereof .
[0014]
14. Method according to claim 12 or 13, characterized in that the hair treatment composition further comprises a composition or an agent for coloring or structuring (shaping) the hair, preferably wherein the coloring agent comprises at least one bleaching agent, at least one coloring compound, or combinations thereof, preferably wherein the at least one bleaching agent is chosen from peroxides, persulfates, perborates, percarbonates, peracids, bromates, their salts, and mixtures thereof; and preferably wherein the at least one coloring compound is chosen from oxidative dyes, direct dyes, pigments, and mixtures thereof.
[0015]
15. A method for changing the color of hair, said method characterized in that it comprises: (a) applying to the hair the hair treatment composition as defined in claim 1; (b) optionally shampooing and/or rinsing hair; (c) applying to the hair a color changing composition comprising at least one bleaching agent, at least one coloring compound, or combinations thereof, prior to, after, or concurrently with application of the hair treatment composition; (d) optionally shampooing and/or rinsing hair; (e) applying to the hair a hair conditioning composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)propylamine, and combinations thereof, or combinations comprising at least two of: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2-aminoethoxy) ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one additive; and (f) optionally shampooing and/or rinsing the hair.
[0016]
16. Hair treatment method, said method characterized in that it comprises: (a) applying to the hair the hair treatment composition as defined in claim 1, wherein the monoamine is: 3-methoxypropylamine; and the at least one carboxylic acid chosen from maleic acid and citric acid; (b) optionally shampooing and/or rinsing hair; (c) preferably further applying to the hair a color altering composition comprising at least one bleaching agent, at least one coloring compound, or combinations thereof, prior to, after, or simultaneously with application of the hair treatment composition, (d) ) then optionally shampoo and/or rinse the hair; (e) applying to the hair a hair conditioning composition comprising: 3-methoxypropylamine; at least one carboxylic acid chosen from maleic acid and citric acid, preferably maleic acid; and at least one additive; and (f) optionally shampooing and/or rinsing the hair.
[0017]
17. Multi-compartment kit for changing the color or shape of hair, said kit characterized in that it comprises: (a) a first compartment containing the hair treatment composition as defined in claim 1; (b) a second compartment containing a hair conditioning composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)propylamine , and combinations thereof, or combinations comprising at least two of: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2-aminoethoxy) )ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one additive; and (c) optionally, one or more additional compartments comprising at least one agent for coloring or for structuring (shaping) the hair.
[0018]
18. Multi-compartment kit for changing the color or shape of hair, said kit, characterized in that it comprises: (a) a first compartment containing the composition for treatment as defined in claim 1, wherein the monoamine is: 3- methoxypropylamine; and the at least one carboxylic acid is chosen from maleic acid and citric acid; and (b) a second compartment containing a hair conditioning composition comprising: 3-methoxypropylamine; at least one carboxylic acid chosen from maleic acid and citric acid; and at least one additive; and optionally, one or more additional compartments comprising at least one agent for coloring or for structuring (shaping) the hair.
[0019]
19. Method for hair treatment, characterized in that it comprises: (a) applying to the hair the treatment composition as defined in claim 1 after the step of reducing of a process for structuring (shaping) hair, (b) optionally leaving the composition for treatment on the hair for a processing time of about 5-20 minutes; (c) optionally drying the hair with an absorbent material or rinsing the hair; and (d) applying a conditioning composition to the hair, the conditioning composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy) - propylamine, and combinations thereof, or combinations comprising at least two of: 3- isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropyl-amine, 3-(2-ethylhexyloxy)-propylamine, 2- (2-aminoethoxy)ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from maleic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one additive; and (e) optionally shampooing and/or rinsing the hair.
[0020]
20. Method according to claim 19, characterized in that the at least one carboxylic acid present in the hair care composition and/or hair conditioning composition is independently chosen from citric acid, malonic acid, oxalic acid, acid malic acid, glutaric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, sebacic acid, glyoxylic acid monohydrate, and combinations thereof, or wherein the at least one carboxylic acid present in the hair care composition and/or in the hair conditioning composition are independently chosen from maleic acid, citraconic acid, fumaric acid, benzoic acid, and combinations thereof, preferably wherein the at least one carboxylic acid present in the hair treatment composition and/or hair conditioning composition are independently chosen from maleic acid, citric acid, and combinations thereof.
[0021]
21. Hair treatment method, said method characterized in that it comprises: (a) applying to the hair the hair treatment composition as defined in claim 1.
[0022]
22. Method according to claim 21, characterized in that the treatment composition further comprises at least one hair coloring agent, preferably further comprising a step of applying to the hair a hair structuring (shape changer) composition comprising at least minus one agent for straightening, relaxing, or permanently waving hair, prior to, after, or concurrently with application of the hair treatment composition.
[0023]
23. A method for changing the color of hair, said method characterized in that it comprises: (a) (1) applying to a portion of hair the treatment composition as defined in claim 1; and at least one hair color altering agent; (b) (2) apply to a portion of hair a treatment composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethyl- hexyloxy)-propylamine, and combinations thereof, or combinations comprising at least two of: 3- isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2- (2-aminoethoxy)ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, maleic acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one solvent; and portions (a)(1) and (a)(2) consisting essentially of different portions of hair; (c) optionally shampooing and/or rinsing hair; (d) optionally shampooing and/or rinsing hair; (e) optionally applying to the hair a hair conditioning composition comprising: at least one monoamine chosen from: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)propylamine , and combinations thereof, or combinations comprising at least two of: 3-isopropoxypropylamine, 3-methoxypropylamine, tris(hydroxymethyl)aminomethane, 3-ethoxypropylamine, 3-(2-ethylhexyloxy)-propylamine, 2-(2-aminoethoxy) )ethanol, 3-butoxypropylamine, and monoethanolamine; at least one carboxylic acid chosen from oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, glycolic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, maleic acid, sebacic acid, benzoic acid, and glyoxylic acid monohydrate, and combinations thereof; and at least one additive; and (f) optionally shampooing and/or rinsing the hair.

类似技术:

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JP2018535268A5|2019-02-28|

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BR112017023380B1|2021-10-13|SYSTEM, COSMETIC COMPOSITION AND METHOD FOR TREATMENT OF KERATIN SUBSTRATES

同族专利:

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公开号 | 公开日

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US20180353409A1|2018-12-13|

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JP6930994B2|2021-09-01|

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US11213470B2|2022-01-04|

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CN108495686A|2018-09-04|

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BR112018010381A2|2018-12-04|

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JP2018535268A|2018-11-29|

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WO2017091797A1|2017-06-01|

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US20220071875A1|2022-03-10|

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EP3380200A1|2018-10-03|

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EP3380200A4|2019-07-17|

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法律状态:
2019-12-03| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-06-29| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-08-17| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/11/2016, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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US201562259586P| true| 2015-11-24|2015-11-24|

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US62/259,586|2015-11-24|

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PCT/US2016/063728|WO2017091797A1|2015-11-24|2016-11-24|Compositions for treating the hair|

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